Multiple substituent effects in the CC reduction of phenyl styryl ketones: cyclic voltammetry as a tool

Annapoorna, S. R.; Rao, M. P.; Sethuram, B.

doi:10.1016/s0022-0728(00)00166-2

Cited by 11 publications

(2 citation statements)

References 11 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The DPP techniques with their optimum parameters were applied to the determination of riboflavin in vegetable and pharmaceutical samples. The standard addition method was applied for the determination of riboflavin content in order to overcome any matrix effect . This method also provides the highest precision.…”

Section: Methodsmentioning

confidence: 99%

Application of Differential Pulse Polarography for Detection of Riboflavin from Pharmaceutical Samples and Vegetables

Patil

Kashid

Kolekar

et al. 2019

Macromolecular Symposia

View full text Add to dashboard Cite

Riboflavin (vitamin B2) plays an important role in living processes as a precursor of coenzymes. The core structure of riboflavin with isoalloxazine ring participates in enzyme‐catalyzed electron transfer processes of many important metabolites. Several methodologies have been developed for the determination of riboflavin, but those methods have disadvantages like long analysis time, consumption of a lot of reagents, and expensiveness. Hence, to overcome these problems, the DPP technique is proposed in this study. The DPP method is used for the quantitative analysis of riboflavin. The experimental conditions are optimized to obtain the best characterized peak in terms of peak height with analytical validation of the method. The proposed methods are applied for the analysis of riboflavin in pharmaceutical samples and vegetables. The riboflavin is found to adsorb and undergo irreversible reduction reaction at the working mercury electrode.

show abstract

Section: Methodsmentioning

confidence: 99%

Application of Differential Pulse Polarography for Detection of Riboflavin from Pharmaceutical Samples and Vegetables

Patil

Kashid

Kolekar

et al. 2019

Macromolecular Symposia

View full text Add to dashboard Cite

show abstract

“…Although their electrochemical reduction has been well studied [17][18][19][20], few researches have been devoted to the anodic oxidation of chalcones [21][22][23][24]. Flavones and flavanonols have been described as the resulting compounds of the anodic oxidations of 2 0 -hydroxychalcones [21][22][23].…”

Section: Introductionmentioning

confidence: 99%

The anodic reactivity of 4,4′-dimethoxychalcone: a synthetic and mechanistic investigation

et al. 2016

View full text Add to dashboard Cite

The anodic oxidation of the 4,4 0 -dimethoxychalcone (DMC) was investigated by different electrochemical methods at a platinum working electrode and in acetonitrile as a solvent. The DMC exhibited a single irreversible anodic peak around 1.6 V versus Ag/AgCl. On the time scale of cyclic voltammetry experiments, the highly reactive radical cation issued from the first electron transfer underwent a second order rate-limiting reaction. The potential imposed electrolyses of DMC led to the formation of a semi-conducting oligomer with 40 % yield. Using different physico-chemicals methods, the structural study confirmed the formation of an o-phenylenevinylene oligomer. The values of the corresponding optical and electrochemical band gaps were calculated to be 3.15 and 2.86 eV, respectively. Finally, a mechanism for the DMC electro-oligomerization was proposed on the basis of the obtained results.

show abstract

Voltammetric techniques for the assay of pharmaceuticals—A review

Gupta

Jain

Radhapyari

et al. 2011

Analytical Biochemistry

463

201

View full text Add to dashboard Cite

Multiple substituent effects in the CC reduction of phenyl styryl ketones: cyclic voltammetry as a tool

Cited by 11 publications

References 11 publications

Application of Differential Pulse Polarography for Detection of Riboflavin from Pharmaceutical Samples and Vegetables

Application of Differential Pulse Polarography for Detection of Riboflavin from Pharmaceutical Samples and Vegetables

The anodic reactivity of 4,4′-dimethoxychalcone: a synthetic and mechanistic investigation

Voltammetric techniques for the assay of pharmaceuticals—A review

Contact Info

Product

Resources

About