Topological phases based on tight‐binding models have been extensively studied in recent decades. By mimicking the linear combination of atomic orbitals in tight‐binding models based on the evanescent couplings between resonators in classical waves, numerous experimental demonstrations of topological phases have been successfully conducted. However, in dielectric photonic crystals, the Mie resonances' states decay too slowly as , leading to intrinsically different physics between tight‐binding models and dielectric photonic crystals. Here, a confined Mie resonance photonic crystal is proposed by embedding perfect electric conductors between dielectric rods, creating the chiral symmetric band structure which ideally matches tight‐binding models with nearest‐neighbour couplings. As a consequence, disentangled band structure spanned by higher atomic orbitals is observed. Moreover, the result provides an effective route to achieve a 3D photonic crystal with a complete photonic bandgap and third‐order topology. The implementation offers a versatile platform for studying exotic higher‐orbital bands and achieving tight‐binding‐like 3D topological photonic crystals.