2008
DOI: 10.1016/j.electacta.2008.02.067
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Multivariate curve resolution as a tool to minimize the effects of electrodic adsorption in normal pulse voltammetry

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Cited by 10 publications
(2 citation statements)
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“…adsorption of an electroactive species via formation of a complex) is at the heart of a few electroanalytical techniques (e.g. Cathodic Stripping Voltammetry [30] or AdSCP [31,32]), overcoming its interfering impact has been a challenge for most voltammetric techniques (including Anodic Stripping Voltammetry) [33][34][35]. The adsorption interference could even jeopardise the validity of large amounts of reported stability constants [36].…”
Section: The Electroanalytical Technique Agnes (Absence Of Gradients and Nernstianmentioning
confidence: 99%
“…adsorption of an electroactive species via formation of a complex) is at the heart of a few electroanalytical techniques (e.g. Cathodic Stripping Voltammetry [30] or AdSCP [31,32]), overcoming its interfering impact has been a challenge for most voltammetric techniques (including Anodic Stripping Voltammetry) [33][34][35]. The adsorption interference could even jeopardise the validity of large amounts of reported stability constants [36].…”
Section: The Electroanalytical Technique Agnes (Absence Of Gradients and Nernstianmentioning
confidence: 99%
“…The application of this method to voltammetric data was also developed in the last few years. [31][32][33][34] The Ni-tartarate complexation system, which forms both inert and labile (i.e., the association-dissociation kinetic of the complex is much faster than the voltammetric measurement) complexes, was investigated in this work. Because of the nature of this system and limits of conventional methods, only the first stability constant of this complexation system was calculated by a conventional method, whilst the soft modeling approach yields two successive complexation Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51666 16471, Iran.…”
Section: Introductionmentioning
confidence: 99%