“…Supercapacitors have emerged as the preferred energy storage device over batteries owing to their higher power density, shorter charging time, and ultra-high cycle stability. To function as next-generation electronic devices available in wearable devices, self-powered sensors, aerospace, and biomedical fields, however, supercapacitors are required to have tolerances to thermal, mechanical, and electrochemical stress as well as electrochemical performances including energy density and power density. − Recently, various novel electrode materials based on nanostructured metal oxides, layered transition metal chalcogenides, and conducting polymer-based hybrid materials have been developed to improve the electrochemical performances of supercapacitors. − Despite the importance of electrolytes on the electrochemical stability and kinetic performance, the development of functional electrolytes that can match the advanced electrode materials lags behind. , Moreover, traditional liquid electrolytes have been shown to be less effective for certain applications due to their mechanical instability, leakage, and safety-related concerns. To address these issues, polymer-based electrolytes, including solid polymer electrolytes and gel polymer electrolytes, , have been proposed. − …”