1997
DOI: 10.1080/10601329708010315
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N-Vinylformamide – Building Block for Novel Polymer Structures

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Cited by 56 publications
(48 citation statements)
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“…Although the convenient PVG precursor, linear polyvinylamine (PVAm), is one of the simplest synthetic amine-containing polymers, it only received significant attention in the 1990's due to the lack of efficient synthetic methods [20]. With the advent of industrial production of N-vinylformamide, and the development of methods of poly(N-vinylformamide) (PNVF) synthesis and its subsequent hydrolysis to PVAm, derivatives of PVAm are becoming more widely available [21]. In line with our interest in material development for chemical and biological defense applications [23,24], in this work we set out to characterize, for the first time, the properties of PVG in basic catalysis of organophosphates, as well as to evaluate the potential of PVG as a bactericide.…”
Section: Introductionmentioning
confidence: 99%
“…Although the convenient PVG precursor, linear polyvinylamine (PVAm), is one of the simplest synthetic amine-containing polymers, it only received significant attention in the 1990's due to the lack of efficient synthetic methods [20]. With the advent of industrial production of N-vinylformamide, and the development of methods of poly(N-vinylformamide) (PNVF) synthesis and its subsequent hydrolysis to PVAm, derivatives of PVAm are becoming more widely available [21]. In line with our interest in material development for chemical and biological defense applications [23,24], in this work we set out to characterize, for the first time, the properties of PVG in basic catalysis of organophosphates, as well as to evaluate the potential of PVG as a bactericide.…”
Section: Introductionmentioning
confidence: 99%
“…Due to the very high molecular weight and the structural similarity to PAAM, PNVF has been studied as a potential candidate as an effective drag reducing agent [71]. Furthermore, PNVF has been introduced as a replacement for acrylamide polymers for industrial application.…”
Section: Poly(n-vinyl Formamide)mentioning
confidence: 99%
“…The reported pKa of PMAA from the literature is 5.4 [70,71]. In contrast, P2VP is only water soluble at low pH and it has a pKa of 4.1 [72,73].…”
Section: Ph Sensitivity Of the Methacrylic Acid/2-vinyl Pyridine (Maamentioning
confidence: 99%