2014
DOI: 10.1002/ejic.201402736
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Na2(smbipy) – A Bipyridine‐Derived Ligand with Chelating Sulfonate Tags and Its 3d Metal Complexes

Abstract: The sulfonated bipyridine derivative disodium 6,6Ј-bis-(sulfonatomethyl)-2,2Ј-bipyridine [Na 2 (smbipy)] was synthesized, and its complexation behaviour towards divalent 3d metals in aqueous solution was explored. The complexes of late 3d metals [M(smbipy)(H 2 O) 2 ]·H 2 O (M = Co, Ni, Zn) and [Cu(smbipy)(H 2 O)] are sparingly soluble in water, and their crystal structures show fourfold equatorial coordination (κ 4 N,NЈ,O,OЈ) of the smbipy ligand. Ammonia-rich solutions of the Ni II and Cu II aqua complexes yi… Show more

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Cited by 4 publications
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