TiO 2 /bauxite-tailings (TiO 2 /BTs) composites were prepared via a chemical liquid deposition method and characterized by X-ray diffractometry (XRD), scanning electronic microscopy (SEM) and N 2 adsorption analysis. The photocatalytic performance of TiO 2 /BTs composites was evaluated with UV-Vis spectrophotometer following the changes of phenol concentration under different illumination time. Effects of the calcination temperature, the pH and the cycles on the photocatalytic activity of TiO 2 /BTs composites were investigated. The composites calcined at 500 and 600 ℃ exhibit the best photocatalytic performance, and the phenol degradation ratios reacting for 40 and 160 min reach 35% and 78% respectively under the same conditions, higher than those of 29% and 76% of the Degussa P25(TiO 2 ). The ability of TiO 2 /BTs 500 (BTs 500 represents bauxite-tailings calcined at 500 ℃) composites to degrade phenol increases with decreasing pH.