This
work presents a practical
methodology to produce multilevel hierarchical structures with precise
control of the structural geometry at every level by combining photo
and nanoimprint lithography processes. The method involves sequential
steps of nanoimprinting of a first deposited polymer layer followed
by nanoimprinting of a second deposited layer of a photoresin and,
afterward, performing on this layer optical lithography by means of
a maskless laser writer to pattern micrometer-size features. A hierarchical
topography is consequently obtained comprising nanopatterns and micropatterns
at different levels designed independently with very high feature
control. The process can be repeated sequentially employing hierarchical
working molds produced on a previous fabrication cycle to produce
multilevel self-similar hierarchical topographies in a sort of fractal
growing manner. The patterning method has broad applicability, as
exemplary demonstration, superhydrophobicity, and anisotropic wetting
behavior are revealed.