“…Among them, CdS/CuInSe 2 is considered as, promising nanomaterials for the development of solar cell owing to its tunable optoelectronic and physico-chemical properties, easy of synthesis, etc., these nanostructured heterojunction thin films can be grown by different routes such as physical and chemical, but achieving the desired stoichiometry, stability and the energy conversion efficiency are the topics of great concern, requiring extensive research. Nevertheless, the issues related to stoichiometry and stability can be resolved up to certain extent by preparing CdS/CuInSe 2 thin films using chemical ion exchange technique which has the merit that the film formed possesses homogenous interface between window (CdS) and absorber (CuInSe 2 ) layer [4,5], but improving the conversion efficiency in nanostructured CdS/CuInSe 2 thin films remains a challenge, extending the scope of the work [6,7]. As solar energy conversion is surface, interface and composition dependent phenomenon, the interface can be modified by ion exchange method, while surface and composition can be improved by providing post deposition treatments like annealing or swift heavy ion (SHI) irradiation [4,[8][9][10][11][12][13].…”