“…The assembly of nanoparticles into 2D or 3D superstructures allows the creation of novel materials and devices with potential applications in, for example, optical switches and filters, chemical and biochemical sensors, photoelectronic devices, and templates for ordered microporous materials [3][4][5][6][7][8][9]. A number of assemblies have been extensively studied, including gravity sedimentation [10], electrophoretic deposition [11], electrostatically induced crystallization [12], colloidal epitaxy [13], convective self-assembly [14], and physical confinement [15,16].…”