The complexity of the valence band structure in p-type PbTe has been shown to enable a significant enhancement of the average thermoelectric figure of merit (zT) when heavily doped with Na. It has also been shown that when PbTe is nanostructured with large nanometer sized Ag 2 Te precipitates there is an enhancement of zT due to phonon scattering at the interfaces. The enhancement in zT resulting from these two mechanisms is of similar magnitude but, in principle, decoupled from one another. This work experimentally demonstrates a successful combination of the complexity in the valence band structure with the addition of nanostructuring to create a high performance thermoelectric material. These effects lead to a high zT over a wide temperature range with peak zT > 1.5 at T > 650 K in Na-doped PbTe/Ag 2 Te. This high average zT produces 30% higher efficiency (300-750 K) than pure Na-doped PbTe because of the nanostructures, while the complex valence band structure leads to twice the efficiency as the related n-type La-doped PbTe/Ag 2 Te without such band structure complexity. Thermoelectric (TE) applications have attracted increasing interest in the last decade as a means to combat the ever growing rate of energy consumption throughout the world. The two main applications for thermoelectric materials are power generation, which utilizes the Seebeck effect, and solid state cooling, which has its roots in the Peltier effect. In recent years, thermoelectric power generation has been a prime interest to the automotive industry 1 as a sustainable and emission free route to vehicular waste heat recovery. The effectiveness of this process is restricted by the overall efficiency of the thermoelectric materials.On a materials level, the efficiency of the thermal to electrical energy conversion is determined by the thermoelectric figure of, where S, s, k E and k L are the Seebeck coefficient, electrical conductivity, and the electronic and lattice components of the thermal conductivity. Since S, s and k E have an intimate relationship with the carrier density, 1,2 the grand challenge in designing thermoelectric materials is the decoupling of electronic and thermal properties. Many methods to achieve a large power factor (S 2 s) or to reduce the thermal conductivity were proven to be successful, but combination of these two effects is difficult. As a result, the current best commercially available thermoelectric materials have a peak zT near unity.A number of mechanisms have been proposed to explain high zT in p-type PbTe. The Tl-doping in PbTe:Tl produces resonant electronic states that enhances the Seebeck coefficient, but reduces hole mobility 3 and has zT $ 1.4 at 500 C. Na-doped PbTe:Na, 4 without resonant states, 5,6 has similarly high zT that Materials Science, California Institute of Technology, Pasadena, CA, 91125, USA. E-mail: jsnyder@caltech.edu
Broader contextThermoelectric generators, which directly convert heat into electricity are being considered for industrial or automotive waste heat recovery. However, th...