2001
DOI: 10.1063/1.1401805
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Nanoscale selective growth of GaAs by molecular beam epitaxy

Abstract: Selective growth of GaAs on a nanoscale SiO2-patterned GaAs(001) substrate by molecular beam epitaxy is reported. Reduction of the lateral dimensions of a SiO2 pattern below the surface diffusion length of an incident Ga atom results in preferential migration from the SiO2 surface to stable bonding configurations at nearby open GaAs substrate surfaces. This intrinsic selectivity is achieved under high growth temperature with low growth rate where surface migration on the SiO2 surface is highly extended. A larg… Show more

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Cited by 47 publications
(36 citation statements)
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“…In all cases, the total GaAs volume deposited in the mask openings is considerably smaller than the estimated volume of a continuous GaAs layer on a mask-free GaAs surface using the same deposition time, indicating that not all Ga adatoms impinging on the SiO 2 areas migrate to the mask openings. According to the estimated volume of GaAs islands deposited at 630°C on a continuous SiO 2 film a sticking coefficient of Ga atoms on SiO 2 of ∼0.13 was estimated [17]. A more recent study found a value of ∼0.007 at 632°C and confirmed the expected exponential dependence on the inverse absolute temperature [20].…”
Section: Theoretical Descriptionsupporting
confidence: 54%
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“…In all cases, the total GaAs volume deposited in the mask openings is considerably smaller than the estimated volume of a continuous GaAs layer on a mask-free GaAs surface using the same deposition time, indicating that not all Ga adatoms impinging on the SiO 2 areas migrate to the mask openings. According to the estimated volume of GaAs islands deposited at 630°C on a continuous SiO 2 film a sticking coefficient of Ga atoms on SiO 2 of ∼0.13 was estimated [17]. A more recent study found a value of ∼0.007 at 632°C and confirmed the expected exponential dependence on the inverse absolute temperature [20].…”
Section: Theoretical Descriptionsupporting
confidence: 54%
“…Regarding the morphology of the GaAs islands selectively grown in circular mask openings it has been found that the height as well as the shape of the islands varies with the diameter of the openings [17]. With decreasing opening diameter the island height increases, because of the larger mask area and related increased number of Ga atoms diffusing from the mask to the GaAs surface (Figure 4(a)).…”
Section: Theoretical Descriptionmentioning
confidence: 97%
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“…Recent progress in lithography technology and its application to molecular beam epitaxy and metalorganic vapor-phase epitaxy (MOVPE) has made accessible a new regime of growth-nanoscale patterned growth and nano-heteroepitaxy [11,12]. In this work, we address the issue of phase instability with a nanoscale patterning technique.…”
Section: Introductionmentioning
confidence: 99%
“…The other sort of approach relies on nanoscale selective area epitaxy (NSAE) on a prepatterned substrate or growth template. The nanopatterning of substrates/templates can be realized by a variety of lithographic or nonlithographic techniques, such as interference lithography, [13,14] anodic oxidation of aluminum to form nanoporous alumina, [15][16][17][18] nanosphere lithography, [19] focused ion beam sputtering, [20] and electron-beam lithography (EBL). [21][22][23][24] At present, state-of-the-art EBL allows the creation of patterns with versatile physical geometry and localization, and homogeneous, tunable size.…”
mentioning
confidence: 99%