Nanosized ammonia borane for solid-state hydrogen storage: Outcomes, limitations, challenges and opportunities

Turani‐I‐Belloto, Kevin; Castilla-Martinez, Carlos A.; Cot, Didier; Petit, Eddy; Benarib, Sofian; Demirci, Umit B.

doi:10.1016/j.ijhydene.2020.11.224

Cited by 22 publications

(11 citation statements)

References 112 publications

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“…These characteristics demonstrated that NH 3 BH 3 was successfully contained within the scaffold. [77] Moreover, tetrahydrofuran was used to successfully infiltrate NH 3 BH 3 . For instance, the porous SHNs were used as hollow fiber by Zhang et al [137] The researchers reported that after NH 3 BH 3 was infiltrated into the surface of hollow fiber using tetrahydrofuran (THF), the NH 3 BH 3 @SHNS had modified textural properties.…”

Section: Techniques For Infiltration Of Hydrides Into Shns Scaffold A...mentioning

confidence: 99%

“…To effectively store hydrogen, as well as to improve the gas‐solid interface during hydrogen adsorption/desorption at high temperatures, hydrogen should be properly confined in a porous scaffold [75,76] . There are so many ways to confine hydrogen efficiently in different kinds of materials or metal hydrides [77] . Different articles and reviews that reported on the confinement of hydrogen in different materials are available.…”

Section: Approaches To Improve Hydrogen Storage Capacitymentioning

confidence: 99%

“…[75,76] There are so many ways to confine hydrogen efficiently in different kinds of materials or metal hydrides. [77] Different articles and reviews that reported on the confinement of hydrogen in different materials are available. For instance, Turani-I-Belloto et al [77] recently worked on nanosized ammonia borane for solid-state hydrogen storage.…”

Section: Confinementmentioning

confidence: 99%

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Progress and Advances in Porous Silica‐based Scaffolds for Enhanced Solid‐state Hydrogen Storage: A Systematic Literature Review

Abdulkadir,

Jalil,

Cheng

et al. 2023

Chemistry An Asian Journal

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Hydrogen plays a crucial role in the future energy landscape owing to its high energy density. However, finding an ideal storage material is the key challenge to the success of the hydrogen economy. Various solid‐state hydrogen storage materials, such as metal hydrides, have been developed to realize safe, effective, and compact hydrogen storage. However, low kinetics and thermodynamic stability lead to a high working temperature and a low hydrogen sorption rate of the metal hydrides. Using scaffolds made from porous materials like silica to confine the metal hydrides is necessary for better and improved hydrogen storage. Therefore, this article reviews porous silica‐based scaffolds as an ideal material for improved hydrogen storage. The outcome showed that confining the metal hydrides using scaffolds based on porous silica significantly increases their storage capacities. It was also found that the structural modifications of the silica‐based scaffold into a hollow structure further improved the storage capacity and increased the affinity and confinement ability of the metal hydrides, which prevents the agglomeration of metal particles during the adsorption/desorption process. Hence, the structural modifications of the silica material into a fibrous and hollow material are recommended to be crucial for further enhancing the metal hydride storage capacity.

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Section: Techniques For Infiltration Of Hydrides Into Shns Scaffold A...mentioning

confidence: 99%

Section: Approaches To Improve Hydrogen Storage Capacitymentioning

confidence: 99%

Section: Confinementmentioning

confidence: 99%

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Progress and Advances in Porous Silica‐based Scaffolds for Enhanced Solid‐state Hydrogen Storage: A Systematic Literature Review

Abdulkadir,

Jalil,

Cheng

et al. 2023

Chemistry An Asian Journal

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“…NaBH4 [49,74,216,236,241], Mg(BH4)2 [42,55,61,70,105,126,132,151,159,207,216,220,224,236,242,243], Ca(BH4)2 [116,216,236,243] and (TM)(BH4)x [150,216], ammonia-borane NH3.BH3 [36,38,63,64,75,85,86,88,90,139,[140][141][142][143][144]153,154,156,162,171,175,197,213,[244]…”

Section: Tm-hydridesmentioning

confidence: 99%

Recent Development in Nanoconfined Hydrides for Energy Storage

Comănescu

2022

IJMS

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Hydrogen is the ultimate vector for a carbon-free, sustainable green-energy. While being the most promising candidate to serve this purpose, hydrogen inherits a series of characteristics making it particularly difficult to handle, store, transport and use in a safe manner. The researchers’ attention has thus shifted to storing hydrogen in its more manageable forms: the light metal hydrides and related derivatives (ammonia-borane, tetrahydridoborates/borohydrides, tetrahydridoaluminates/alanates or reactive hydride composites). Even then, the thermodynamic and kinetic behavior faces either too high energy barriers or sluggish kinetics (or both), and an efficient tool to overcome these issues is through nanoconfinement. Nanoconfined energy storage materials are the current state-of-the-art approach regarding hydrogen storage field, and the current review aims to summarize the most recent progress in this intriguing field. The latest reviews concerning H2 production and storage are discussed, and the shift from bulk to nanomaterials is described in the context of physical and chemical aspects of nanoconfinement effects in the obtained nanocomposites. The types of hosts used for hydrogen materials are divided in classes of substances, the mean of hydride inclusion in said hosts and the classes of hydrogen storage materials are presented with their most recent trends and future prospects.

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“…In this regard, several hydrogen storage technology areas are reviewed and analyzed based on the perspective of knowledge recombination. In recent years, some review researches of hydrogen storage technology have been published, covering storage options (Elberry et al, 2021), materials and process design (Chanchetti et al, 2016;Turani-I-Belloto et al, 2021), energy carriers (Aziz, 2021) and fuel cells (Eriksson and Gray, 2017;Gong and Verstraete, 2017). Most studies have future-oriented feature, and have proved helpful to investigate development trends of hydrogen storage technology.…”

Section: Introductionmentioning

confidence: 99%

Exploring Technological Solutions for Onboard Hydrogen Storage Systems Through a Heterogeneous Knowledge Network: From Current State to Future Research Opportunities

Shi

Cai

et al. 2022

Front. Energy Res.

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With the imminent threat of the energy crises, innovation in energy technologies is happening world-wide. The aim is to reduce our reliance on fossil fuels. Electric vehicles with fuel-cells that use hydrogen as an energy carrier are touted to be one of the most important potential replacements of the gasoline vehicle in both future transportation scenarios and emerging smart energy grids. However, hydrogen storage is a major technical barrier that lies between where we are now and the mass application of hydrogen energy. Further exploration of onboard hydrogen storage systems (OHSS) is urgently needed and, in this regard, a comprehensive technology opportunity analysis will help. Hence, with this research, we drew on scientific papers and patents related to OHSS and developed a novel methodology for investigating the past, present, and future development trends in OHSS. Specifically, we constructed a heterogeneous knowledge network using a unique multi-component structure with three core components: hydrogen carriers, hydrogen storage materials, and fuel cells. From this network, we extracted both the developed and underdeveloped technological solutions in the field and applied a well-designed evaluation system and prediction model to score the future development potential of these technological solutions. What emerged was the most promising directions of research in the short, medium, and long term. The results show that our methodology can effectively identify technology opportunities in OHSS, along with providing valuable decision support to researchers and enterprise managers associated with the development and application of OHSS.

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Nanosized ammonia borane for solid-state hydrogen storage: Outcomes, limitations, challenges and opportunities

Cited by 22 publications

References 112 publications

Progress and Advances in Porous Silica‐based Scaffolds for Enhanced Solid‐state Hydrogen Storage: A Systematic Literature Review

Progress and Advances in Porous Silica‐based Scaffolds for Enhanced Solid‐state Hydrogen Storage: A Systematic Literature Review

Recent Development in Nanoconfined Hydrides for Energy Storage

Exploring Technological Solutions for Onboard Hydrogen Storage Systems Through a Heterogeneous Knowledge Network: From Current State to Future Research Opportunities

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