We synthesized a new random conjugated copolymer (RCCP)
containing
2,6-bis(4-chlorophenyl)-4-phenylpyridine, carbazole, diphenylamine,
and diphenyl sulfone. Subsequently, a Bi2S3-microrod-dispersed
phosphoric-acid-doped random conjugated copolymer composite membrane
was prepared and its properties were studied with respect to its suitability
as a polymer electrolyte in fuel cells (PEMFCs). The monomer 2,6-bis(4-chlorophenyl)-4-phenylpyridine
was successfully synthesized through the Hantsh pyridine synthesis.
The RCCP polymer was effectively synthesized through the Friedel–Crafts
reaction and characterized by Fourier transform infrared (FT-IR) spectroscopy,
NMR spectroscopy, and scanning electron microscopy. Bi2S3 MRs were prepared by the hydrothermal technique, and
transmission electron microscopy (TEM) and standard error of the mean
(SEM) analyses revealed a rod-like morphology of Bi2S3. Neat RCCP and 1, 2, 3, and 5 wt % Bi2S3 microrod-embedded RCCP membranes were prepared and studied for their
swelling ratio (SR), water uptake (WU), oxidative stability (OS),
thermogravimetry (TGA), proton conductivity (PC), and ion-exchange
capacity (IEC), and they exhibited tensile stress and elongation at
break values of 2.08 MPa and 310.17%, respectively. The 3% Bi2S3 microrod-loaded RCCP membrane presented an ion-exchange
capacity value of 1.117 mmol/g–1 and a proton conductivity
of 1.74 × 10–2 S/cm–1 at
90 °C. The Arrhenius plot of proton conductivity with temperature
showed that the proton transport in the Bi2S3/RCCP microcomposite films occurred by both vehicular and the Grotthuss
mechanisms.