Naphthalenedicarboxylate based metal organic frameworks: Multifaceted material

Baruah, Jubaraj B.

doi:10.1016/j.ccr.2021.213862

Cited by 13 publications

(8 citation statements)

References 178 publications

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“…As one of the widely used dicarboxylate ligands, many naphthalene dicarboxylate coordination polymers have been reported to exhibit diverse structures and physical properties. 25 Generally, there are four kinds of main carboxylate binding modes which have been well demonstrated in a recent review. 25 In compound 1 , the DClbc ligand shows a simple and relatively rare binding mode to link the Co ions, while there are two binding modes of the ndc ligand in 2 .…”

Section: Resultsmentioning

confidence: 99%

“…25 Generally, there are four kinds of main carboxylate binding modes which have been well demonstrated in a recent review. 25 In compound 1 , the DClbc ligand shows a simple and relatively rare binding mode to link the Co ions, while there are two binding modes of the ndc ligand in 2 . In addition, the ndc ligand (9.1 Å) is much longer than the DClbc ligand (6.9 Å).…”

Section: Resultsmentioning

confidence: 99%

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Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt(ii) coordination polymers via distinct dicarboxylates

et al. 2022

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt(ii) coordination polymers via distinct dicarboxylates

et al. 2022

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“…The promising aspects of naphthalene-based MOFs generated from the orientations of the naphthalene units have provided control of radioluminescent properties, and the role of the naphthalene linkers will continue to provide large numbers of variations of radioluminescent MOFs for radiation-responsive use in the future. [63] Anthracene (C 14 H 10 ) crystals have long served as a gold standard in the field of commercial organic scintillators, [64] notably within the BC-400 series by Saint-Gobain. This recognition is particularly attributed to its excellence in detecting low-energy 𝛽-rays and neutrons, boasting the highest recorded light output (17 400 photons MeV −1 ) among all organic crystal scintillators.…”

Section: Linker-based Emissionsmentioning

confidence: 99%

Radiation‐Responsive Metal–Organic Frameworks: Fundamentals and Applications

Chen,

Wang,

Peng

et al. 2023

Adv Funct Materials

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Metal–organic frameworks (MOFs), formed by the coordination of metal nodes and organic linkers, constitute a class of multifunctional materials with unprecedentedly high chemical/structural designability. Through properly harnessing the synergistic interplay between high atomic number nodes and functional linkers, radiation‐responsive MOFs have recently come on the scene, which can convert ionizing radiations (e.g., X‐ray, γ‐ray, β‐ray, α‐particle, and neutron) into electrical charges or visible light. Given the attributes of cost‐effectiveness, robust environmental stability, extensive chemical tunability, and diverse functionalities, cutting‐edge radiation‐responsive MOFs with remarkable electronic and optical properties have emerged as promising substitutes for conventional organic and inorganic radiation‐responsive substances in applications across biomedicine and technology. This review article documents recent advancements in radiation‐responsive MOFs by elucidating the foundational mechanisms governing electronic transport and photon conversion within frameworks through inherent node–linker and host–guest interactions prompted by high‐energy radiation. Furthermore, this review delves into state‐of‐the‐art applications that leverage newly formulated radiation‐responsive MOFs, capitalizing on precisely engineered component interactions to achieve efficient energy absorption, conversion, and emission. The rationale behind these developments is concluded and future opportunities for expanding the research of radiation‐responsive MOFs are simultaneously highlighted.

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“…Depending on the nature of the carboxylato ligands and in combination with the choice of metal ions, the resultant metal complexes may present interesting properties from many points of view, such as magnetic, photochemical, and biological properties [1][2][3][4][5][6][7][8]. Among the carboxylato ligands, the acetato ligands and their derivatives are the most studied ones, leading to a variety of metal complexes, nuclearities and properties [7][8][9].…”

Section: Introductionmentioning

confidence: 99%

Metal Complexes with Naphthalene-Based Acetic Acids as Ligands: Structure and Biological Activity

2023

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Naproxen (6–methoxy–α–methyl–2–naphthaleneacetic acid), 1–naphthylacetic acid, 2–naphthylacetic acid and 1–pyreneacetic acid are derivatives of acetic acid bearing a naphthalene-based ring. In the present review, the coordination compounds of naproxen, 1– or 2–naphthylacetato and 1–pyreneacetato ligands are discussed in regard to their structural features (nature and nuclearity of metal ions and coordination mode of ligands), their spectroscopic and physicochemical properties and their biological activities.

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Naphthalenedicarboxylate based metal organic frameworks: Multifaceted material

Cited by 13 publications

References 178 publications

Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt(ii) coordination polymers via distinct dicarboxylates

Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt(ii) coordination polymers via distinct dicarboxylates

Radiation‐Responsive Metal–Organic Frameworks: Fundamentals and Applications

Metal Complexes with Naphthalene-Based Acetic Acids as Ligands: Structure and Biological Activity

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