NASICON-type Na3V2(PO4)3 as a new positive electrode material for rechargeable aluminium battery

Nacimiento, Francisco; Cabello, Marta; Alcántara, Ricardo; Lavela, Pedro; Tirado, J.L.

doi:10.1016/j.electacta.2017.12.040

Cited by 55 publications

(36 citation statements)

References 35 publications

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“…NASICON‐type Na 3 V 2 (PO 4 ) 3 (NVP) was studied by Nacimiento et al with rigorous detail using 0.1 m AlCl 3 aqueous electrolytes . NVP/carbon nanocomposites were prepared by wet ball‐milling in order to 1) enhance the conductivity and 2) slow down dissolution of NVP in the electrolyte.…”

Section: Aqueous Rechargeable Electrodes For Al‐ion Storagesupporting

confidence: 66%

“…Electrode performances can degrade if the transition‐metal elements forming the redox‐active centers of intercalation materials dissolve in aqueous electrolytes. This has been observed to occur in ZIAB and AIAB electrodes containing vanadium and manganese . Normally, while interacting with water molecules, transition‐metal elements will exhibit different stable phases depending on both the pH and the applied potential.…”

Section: Challenges and Solutionsmentioning

confidence: 99%

See 1 more Smart Citation

Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook

Verma

Kumar

Manalastas

et al. 2018

Advanced Sustainable Systems

159

149

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www.advsustainsys.comion-based chemistries exclusively. Though few reviews document electrode materials and their performances for rechargeable aqueous Zn-and Al-ion batteries, [23,[25][26][27] a comprehensive understanding of ion storage mechanisms remains poorly enunciated. We believe the key to successful implementation of MV-ion batteries requires a simultaneous understanding of various elemental chemistries, in context with each other. Here, we summarize reported electrochemical reactions for Zn-ion and Al-ion electrodes. We compare activation mechanisms for ion transport and the role of water in various crystal lattices, and analyze specific challenges for electrode materials such as limited cation mobility, spontaneous dissolution, poor cycling, O 2 interaction, untoward proton/hydronium coinsertion, ineffective electrode-electrolyte interface formation, and current-collector corrosion. We illustrate how these challenges are dependent on some of the battery design parameters, with an aim to find optimized solutions or alternative strategies to increase the viability of Zn-ion aqueous batteries (ZIABs) and Al-ion aqueous batteries (AIABs) in BESS. Aqueous Rechargeable Electrodes for Zn-Ion StorageIn this review, we discuss rechargeable electrodes which can insert Zn 2+ ions. Since, electrodes for zinc-nickel batteries, [28,29] alkaline Zn-MnO 2 batteries, [30,31] or the hybrid zinc aqueous batteries, [32] store other ions (and not Zn 2+ ), we do not discuss these systems here. Majority of the literature for ZIAB electrodes spans various polymorphs of manganese dioxide, [33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48] vanadium compounds, [49][50][51][52][53][54][55][56][57][58][59][60][61] and hexacyanoferrates, [62][63][64][65] and we discuss few Zn 2+ storage mechanisms for these electrodes. Additionally, we also highlight key similarities, missing links in the reaction mechanism, and the role of water, if any. 2.

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Section: Aqueous Rechargeable Electrodes For Al‐ion Storagesupporting

confidence: 66%

Section: Challenges and Solutionsmentioning

confidence: 99%

Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook

Verma

Kumar

Manalastas

et al. 2018

Advanced Sustainable Systems

159

149

View full text Add to dashboard Cite

show abstract

“…The hybrid Na−Al ion battery with 1.0 M NaAlCl 4 operates at 1.25 V by delivering a cathodic capacity of 99 mA h g −1 at a current rate of C/10 . It is noticeable that, in non‐aqueous electrolyte, the electrochemical reaction comprises the reversible intercalation of Na + into Na 3 V 2 (PO 4 ) 3 , which is different from that established in the cell with aqueous electrolyte ,. These results demonstrates once again the importance of the choice of appropriate electrolyte in order to control the electrochemical reaction.…”

Section: Structural Matrices Suitable For Li+ Na+ and Mg2+ Intercalamentioning

confidence: 93%

Lithium versus Mono/Polyvalent Ion Intercalation: Hybrid Metal Ion Systems for Energy Storage

Stoyanova

Koleva

2018

The Chemical Record

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The energy storage by redox intercalation reactions is, nowadays, the most effective rechargeable ion battery. When lithium is used as intercalating agents, the high energy density is achieved at an expense of non-sustainability. The replacement of Li with cheaper monovalent ions enables to make greener battery alternatives. The utilization of polyvalent ions instead of Li permits to multiplying the battery capacity. Contrary to Li , the realization of quick and reversible intercalation of bigger monovalent and of polyvalent ions is a scientific challenge due to kinetic constraints, polarizing ion effects and Coulomb interactions. Herein we provide a vision how to make the intercalation of these ions feasible. The idea is to perform dual intercalation of ions having different charges, radii, preferred coordination and diffusion pathway topology. All these features are demonstrated by the recent knowledge on selective and non-selective intercalation properties of oxides and polyanion compounds with layered and tunnel structures. Based on dual intercalation properties, the fabrication of hybrid metal ion batteries is presented and discussed.

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“…Due to the promising NASICON structure, NVP attracted extensive interests not only for SIBs, but also for hybrid LIBs, emerging ZIBs and AIBs . Li et al applied NVP as the cathode for aqueous ZIBs.…”

Section: Vanadium Phosphatesmentioning

confidence: 99%

“…Due to the promising NASICON structure, NVP attracted extensive interests not only for SIBs, but also for hybrid LIBs, [244][245][246] emerging ZIBs [214] and AIBs. [247] Li et al [214] applied NVP as the cathode for aqueous ZIBs. A reversible capacity of 97 mAh g −1 at 0.5 C with a relatively high discharge voltage plateau of 1.1 V was obtained, which retained 74% after 100 cycles.…”

Section: Na 3 V 2 (Po 4 )mentioning

confidence: 99%

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Xiong

Meng

et al. 2020

Adv Funct Materials

335

212

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The emerging electrochemical energy storage systems beyond Li‐ion batteries, including Na/K/Mg/Ca/Zn/Al‐ion batteries, attract extensive interest as the development of Li‐ion batteries is seriously hindered by the scarce lithium resources. During the past years, large amounts of studies have focused on the investigation of various electrode materials toward emerging metal‐ion batteries to realize high energy density, high power density, and a long cycle life. In particular, vanadium‐based nanomaterials have received great attention. Vanadium‐based compounds have a big family with different structures, chemical compositions, and electrochemical properties, which provide huge possibilities for the development of emerging electrochemical energy storage. In this review, a comprehensive overview of the recent progresses of promising vanadium‐based nanomaterials for emerging metal‐ion batteries is presented. The vanadium‐based materials are classified into four groups: vanadium oxides, vanadates, vanadium phosphates, and oxygen‐free vanadium‐based compounds. The structures, electrochemical properties, and modification strategies are discussed. The structure–performance relationships and charge storage mechanisms are focused on. Finally, the perspectives about future directions of vanadium‐based nanomaterials for emerging energy storage devices are proposed. This review will provide comprehensive knowledge of vanadium‐based nanomaterials and shed light on their potential applications in emerging energy storage.

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NASICON-type Na3V2(PO4)3 as a new positive electrode material for rechargeable aluminium battery

Cited by 55 publications

References 35 publications

Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook

Progress in Rechargeable Aqueous Zinc‐ and Aluminum‐Ion Battery Electrodes: Challenges and Outlook

Lithium versus Mono/Polyvalent Ion Intercalation: Hybrid Metal Ion Systems for Energy Storage

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

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