Ramie-fiber-reinforced polymer composites (RFRP) have the advantages of low price and low energy consumption, but they have high hydrophilicity due to their special chemical composition. In order to study the effect of water absorption on the performance degradation of RFRP in a hydrothermal environment, the authors prepared RFRP sheets by compression molding. Manufactured composites were exposed to a hydrothermal environment with a temperature of 40 °C and a humidity of 50% RH, 85% RH and 98% RH to study the water absorption and diffusion, mechanical properties (tensile properties, flexural properties and shear properties) of the RFRP, and their mechanical properties after drying. The research shows that the equilibrium moisture absorption rate of RFRP is mainly affected by the ambient humidity. The moisture absorption and diffusion of ramie-fiber-reinforced polymer composites (RFRP) in a hydrothermal environment conform to Fick’s law. Before reaching the moisture absorption equilibrium (1~2 weeks), the mechanical properties decline rapidly, and then tend to be flat, and the mechanical properties of the RFRP decrease significantly with the increase in humidity; the water molecules reduce the interfacial bonding performance and the modulus degradation degree of RFRP in the hydrothermal environment is greater than that of strength. After the samples were completely dried, the mechanical properties of the RFRP rebounded greatly, but less than the initial value, and the hydrothermal environment produced irreversible changes to the substrates.