Nature of the carbonium ion. II. Furfuryl cation from a thiocyanate isomerization

Spurlock, Langley A.; Fayter, Richard G.

doi:10.1021/jo01264a061

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Introduction1

Syntheses With Lantern Rods1

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2016

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Cited by 13 publications

(2 citation statements)

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“…It is also worthwhile to mention exceptions to occurrence of the reaction such that cinnamyl thiocyanate is known not to isomerize to the isothiocyanate [11,12] and furfuryl thiocyanate also fails to isomerize under various conditions [13].…”

Section: Introductionmentioning

confidence: 99%

Experimental and theoretical studies on the isomerization of allyl thiocyanate to allyl isothiocyanate

et al. 1997

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Section: Introductionmentioning

confidence: 99%

Experimental and theoretical studies on the isomerization of allyl thiocyanate to allyl isothiocyanate

et al. 1997

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“…Reduction is performed using SnCl2×2H 2 O. The isothiocyanates used are metachlorophenyl isothiocyanate (I) [13] isothiocyanate (II) [14], which were prepared by known procedures. To convert thioureas into guanidines, NaIO 4 and three amines are required: morpholine (α), m-toluidine (β), and benzylamine (γ).…”

Section: Syntheses With Lantern Rodsmentioning

confidence: 99%

Solid-phase synthesis for beginners: Choice of tools and techniques for implementation of multistage transformations

Бабаев

2010

Russ J Gen Chem

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Abstract-Several mini-libraries were prepared by solid-phase synthesis: C,N-substituted glycines (1) and 2,5-diaminobenzoic acids (2) using Wang resin as well as diarylthioureas (3) and diaryl-guanidines (4) using Rink resin. Comparative analysis of the instruments and technique for these reactions was provided by applying glass vials with filters (BillBoard kit) to prepare the class (1), the tea-bag technique for the class (2), and plastic rods (Lanterns) for the classes (3) and (4). All reactions (supplied with detailed protocols) were optimized for use as a tool of practical student education.

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ChemInform Abstract: CARBONIUM‐IONEN 2. MITT. FURFURYLKATION AUS DER ISOMERISIERUNG VON THIOCYANAT‐ISOTHIOCYANAT

Spurlock¹,

Fayter²

1970

Chemischer Informationsdienst. Organische Chemie

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Nature of the carbonium ion. II. Furfuryl cation from a thiocyanate isomerization

Cited by 13 publications

References 0 publications

Experimental and theoretical studies on the isomerization of allyl thiocyanate to allyl isothiocyanate

Experimental and theoretical studies on the isomerization of allyl thiocyanate to allyl isothiocyanate

Solid-phase synthesis for beginners: Choice of tools and techniques for implementation of multistage transformations

ChemInform Abstract: CARBONIUM‐IONEN 2. MITT. FURFURYLKATION AUS DER ISOMERISIERUNG VON THIOCYANAT‐ISOTHIOCYANAT

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