2014
DOI: 10.5741/gems.50.1.30
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Near-Colorless HPHT Synthetic Diamonds from AOTC Group

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Cited by 22 publications
(29 citation statements)
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“…We theoretically predict a charge transition level to be 2.71 eV above the valence band maximum. This suggests that photoionization could contribute to spectra by illumination into the phonon sideband under our pump at 450 nm (2.76 eV), as seen with NV 35,36 and SiV centers 37 . We observed fluorescence instability in some centers under blue illumination (Supplemental Materials), which could indicate the presence of an alternate charge state.…”
Section: Discussionmentioning
confidence: 80%
“…We theoretically predict a charge transition level to be 2.71 eV above the valence band maximum. This suggests that photoionization could contribute to spectra by illumination into the phonon sideband under our pump at 450 nm (2.76 eV), as seen with NV 35,36 and SiV centers 37 . We observed fluorescence instability in some centers under blue illumination (Supplemental Materials), which could indicate the presence of an alternate charge state.…”
Section: Discussionmentioning
confidence: 80%
“…As point defects, dislocations, and other extended defects are believed to be the dominant sources of strain in type IIa diamonds (Fisher et al, 2006), HPHT-synthesized diamonds may also exhibit lower strain than their CVD-grown counterparts. While dislocation densities of ≈10 4 − 10 6 cm −2 are typical in CVD-grown diamonds (Achard et al, 2014), certain HPHT-synthesized diamonds can demonstrate dislocation densities of ≈100-1000 cm −2 (Martineau et al, 2009;Tallaire, Mille et al, 2017) and substantially lower strain (D'Haenens-Johansson et al, 2014.…”
Section: Diamond Synthesis and High-pressure-high-temperature (Hphmentioning
confidence: 98%
“…Occasionally, metallic inclusions are present in sufficient concentration in a synthetic diamond to produce a detectable magnetic reaction. The absence of these metallic inclusions, or the absence of a magnetic response, does not exclude HPHT synthetic origin, as research has shown that the magnetic attraction was consistently detected only in the SI-I clarity range (D'Haenens-Johansson et al, 2014). A diamond dealer once related to us the prac-…”
Section: Hpht Synthetic Diamond Growthmentioning
confidence: 99%
“…Blue HPHT synthetics result from the presence of boron within the growth chamber. Colorless HPHT synthetics are reportedly sold as-grown without post-growth color modification (D'Haenens-Johansson et al, 2014), and they often contain small amounts of boron, which does not alter their color (but does impart luminescence).…”
Section: Analysis Of Existing Datamentioning
confidence: 99%