New annual radiocarbon calibration data offer a resolution to controversial dating of the Bronze Age eruption of Thera.

The calibration of radiocarbon dates by means of a master calibration curve has been invaluable to Earth, environmental and archeological sciences, but the fundamental reason for calibration is that atmospheric radiocarbon content varies because of changes in upper atmosphere production and global carbon cycling. Improved instrumentation has contributed to high-resolution (interannual) radiocarbon activity measurements, which have revealed sudden and anomalous activity shifts previously not observed at the common resolution of 5-10 years of most of the calibration scale. One such spike has been recently reported from tree rings from Japan and then again in Europe at A.D. 774-775, for which we report here our efforts to both replicate its existence and determine its spatial extent using tree rings from larch at high latitude (northern Siberia) and bristlecone pine from lower latitude (the White Mountains of California). Our results confirm an abrupt~15‰ 14 C activity increase from A.D. 774 to 776, the size and now the hemispheric extent of which suggest that an extraterrestrial influence on radiocarbon production is most likely responsible.

Radiocarbon content in tree rings can be an excellent proxy of the past incoming cosmic ray intensities to Earth. Although such past cosmic ray variations have been studied by measurements of14C contents in tree rings with ≥10-y time resolution for the Holocene, there are few annual14C data. There is a little understanding about annual14C variations in the past, with the exception of a few periods including the AD 774−77514C excursion where annual measurements have been performed. Here, we report the result of14C measurements using the bristlecone pine tree rings for the period from 5490 BC to 5411 BC with 1- to 2-y resolution, and a finding of an extraordinarily large14C increase (20‰) from 5481 BC to 5471 BC (the 5480 BC event). The14C increase rate of this event is much larger than that of the normal grand solar minima. We propose the possible causes of this event are an unknown phase of grand solar minimum, or a combination of successive solar proton events and a normal grand solar minimum.

Peat deposits in Greenland and Denmark were investigated to show that high-resolution dating of these archives of atmospheric deposition can be provided for the last 50 years by radiocarbon dating using the atmospheric bomb pulse. 14C was determined in macrofossils from sequential one cm slices using accelerator mass spectrometry (AMS). Values were calibrated with a general-purpose curve derived from annually averaged atmospheric 14CO2 values in the northernmost northern hemisphere (NNH, 30°–90°N). We present a thorough review of 14C bomb-pulse data from the NNH including our own measurements made in tree rings and seeds from Arizona as well as other previously published data. We show that our general-purpose calibration curve is valid for the whole NNH producing accurate dates within 1–2 years. In consequence, 14C AMS can precisely date individual points in recent peat deposits within the range of the bomb-pulse (from the mid-1950s on). Comparing the 14C AMS results with the customary dating method for recent peat profiles by 210Pb, we show that the use of 137Cs to validate and correct 210Pb dates proves to be more problematic than previously supposed.As a unique example of our technique, we show how this chronometer can be applied to identify temporal changes in Hg concentrations from Danish and Greenland peat cores.

Significance Archaeological evidence from Sonora, Mexico, indicates that the earliest widespread and recognizable group of hunter-gatherers (“Clovis”) were in place ∼13,390 y ago in southwestern North America. This is the earliest well-documented population on the continent and suggests that the unique Clovis artifact style originated in the southwest or south central part of the continent, well south of the Arctic gateways into the continent. These hunters targeted gomphotheres, an elephant common in south and central North America, but unknown in association with humans or at this late age in North America.