Comprehensive (d,k) sequences study is presented, complemented with the design of a new, efficient, Run-Length Limited (RLL) code. The new code belongs to group of constrained coding schemas with a coding rate of R = 2/5 and with the minimum runlength between two successive transitions equal to 4. Presented RLL (4, ∞) code uses channel capacity highly efficiently, with 98.7% and consequently it achieves a high-density rate of DR = 2.0. It is implying that two bits can be recorded, or transmitted with one transition. Coding techniques based on the presented constraints and the selected coding rate have better efficiency than many other currently used codes for high density optical recording and transmission.