Neuere Methoden der präparativen organischen Chemie IV Synthesen mit s‐Triazin

Grundmann, Ch.

doi:10.1002/ange.19630750902

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2010

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Cited by 19 publications

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“…Heterocycles have gained increased significance in modern chemistry . Among N-containing heterocycles, 1,3,5-triazine derivatives , have found numerous industrial applications as pharmaceuticals, liquid crystals, reactive dyes, and organic light-emitting diodes (OLEDs) . However, the efficient syntheses of polyfunctional 1,3,5-triazines, including dimeric and trimeric triazine derivatives, remain a synthetic challenge.…”

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confidence: 99%

Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine−Magnesium Exchange

2010

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Functionalized iodo- and diiodo-1,3,5-triazine derivatives readily undergo an I/Mg exchange with BuMgCl, sBuMgCl, or OctMgBr at low temperatures furnishing 2-magnesiated and 2-zincated 1,3,5-triazines (after transmetalation with ZnCl(2)). This method also offers a convenient access to dimagnesiated triazines. Furthermore, it allows the preparation of functionalized 1,3,5-triazinyl dimers and trimers, interesting for their opto-electronic properties.

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