Presented is the observation of a quadratic temperature dependence of the Cs 0 -0 ground state hyperfine resonance frequency in a single Neon (Ne) buffer gas vapour microcell. The inversion temperature, expected to be theoretically independent of the buffer gas pressure, is measured to be about 808C for two different samples. A proposal to develop chip scale atomic clocks with improved long-term frequency stability, simpler configuration (a single buffer gas instead of a buffer gas mixture) and then relaxed constraints on pressure accuracy during the cell filling procedure is presented.Introduction: In the last decade, the significant advances in micromachining technologies and semiconductor lasers combined with the coherent population trapping phenomenon [1] has allowed the development of chip scale atomic clocks (CSAC) [2,3]. These miniature time references, exhibiting typical frequency stability of the order of 10 210 at 1 s and 10 211 at 1000 s to 1 day for a volume of a few tens of cm 3 and a power consumption of 150 mW, are of great interest in various portable battery-operated applications, such as navigation receivers and telecommunication systems.The heart of these miniature frequency standards usually consists of a microfabricated alkali vapour cell, formed in a wafer of silicon with glasses bonded to both sides. The cell is filled with buffer gases in order to prevent wall relaxation, increase the atom -light interaction time, and reduce the Doppler broadening [4]. Nevertheless, slight interactions taking place between alkali atoms and buffer gases cause a frequency shift of the hyperfine transition of the atom. This shift Dn, of the order of several hundreds of Hz per Torr, is expected to be dependent on the nature of the gas, pressure and operating temperature T, and can be expressed as in [5]: