Rare earth doped materials have the advantages of high fluorescence intensity and high conversion efficiency due to the unique electronic layer structure of rare earth ions. Thus, they have been widely used in many significant fields such as bioimaging, 1,2 lighting, 3,4 laser, 5,6 and amplifier. 7,8 However, the emission of rare earths ion generally involves the f-f transition which is less affected by the environment. As a result, the luminescence peak shape of rare earths ion is narrow. How to broaden and change the luminescence of rare earth ions has become an important research topic for interdisciplinary researchers. As a typical example, Er 3+ -doped glass and fiber have been extensively studied because its near-infrared (NIR) luminescence locates at the safe wavelength for the human eye and coincides with the lowest-loss window of silica fiber. Recent studies have shown that broadband NIR emission from Er 3+ is mainly limited to the heavy metal oxide glasses