Structural optimization of activated
carbon (AC) mainly relies
on experience, which depends on the intrinsic structure of biochar,
processing conditions, and the interplay of both parties. A fundamental
understanding of the pore structure evolution related to the intrinsic
structure and composition remains a challenge. In this work, spent
mushroom substrate, a rapidly growing byproduct of the mushroom cultivation
industry, is used as model biomass to prepare AC under CO2 activation. The structure and composition of the AC products with
different activation durations were systematically analyzed with several
characterization techniques including N2 adsorption–desorption,
scanning electron microscopy, X-ray diffraction, and Raman spectroscopy.
A multipeak separation method is developed that enables quantitative
analysis of carbonized lignin and carbonized cellulose. A peak area
ratio parameter is proposed to describe the retention of cellulose.
It is revealed that higher retention of carbonized cellulose corresponds
to a larger Brunauer–Emmett–Teller (BET) surface area,
demonstrating the dominant role of cellulose in the pore structure
development process. This work not only provides a qualitative correlation
between cellulose and rich porous structure but also offers a new
quantitative tool to understand the structure–composition relationship
during the pore evolution process.