2012
DOI: 10.1002/pen.23311
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New Polyurethane‐based magnetostrictive composites: Dynamical mechanical properties

Abstract: Polyurethane‐based magnetostrictive composites containing between 30 and 70 wt% Terfenol‐D have been prepared in order to obtain better and tailored dynamic‐mechanical properties. The thermal and mechanical properties of polyurethanes with different chemical compositions were first analyzed to determine the most adequate one to prepare the composite materials. Calorimetric analysis indicates that the amount of crystallites increased in presence of Terfenol‐D. Dynamic‐mechanical properties have also been determ… Show more

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Cited by 4 publications
(5 citation statements)
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“…Due to the intrinsic thermodynamic incompatibility of so segment and hard segment in polyurethanes, its thermal and mechanical behaviours are closely relevant to the ratio of the two segments, the density of chemical crosslinking and the degree of micro-phase separation. 35,36 DMTA technique is more sensitive to measure glass transition temperature (T g ) than DSC, and can provide information about side-chain or main-chain motions in specic regions of the polymer and local mode relaxation. 31 Fig.…”
Section: Dynamic Mechanical Thermal Analysis (Dmta)mentioning
confidence: 99%
“…Due to the intrinsic thermodynamic incompatibility of so segment and hard segment in polyurethanes, its thermal and mechanical behaviours are closely relevant to the ratio of the two segments, the density of chemical crosslinking and the degree of micro-phase separation. 35,36 DMTA technique is more sensitive to measure glass transition temperature (T g ) than DSC, and can provide information about side-chain or main-chain motions in specic regions of the polymer and local mode relaxation. 31 Fig.…”
Section: Dynamic Mechanical Thermal Analysis (Dmta)mentioning
confidence: 99%
“…TDI and PEG are usually used to prepare polyurethane lms and foams. [18][19][20] The process for the preparation of the FPU sponge is shown in Scheme 1(b). The FPU sponge was synthesized with a simple and quick method that used water as the foaming agent under catalysis without solvent.…”
Section: Synthesis and Characterization Of Polyurethane Spongesmentioning
confidence: 99%
“…The popularity of PU elastomers actually derives from the fact that their functional properties can be easily tuned by the choice of reaction components, preparation and processing conditions. The variability of the composition of macrodiols: difference in length and mainly in the constitution (based on polyether, polyester, polycarbonate, polybutadiene and their combinations); chemical nature of diisocyanates (aromatic, aliphatic or cycloaliphatic), and a wide choice of chain extenders (mainly short diols, as butane‐1,4‐diol), together with the possibility to modify the preparation procedure offer an almost infinite variety in end‐use (often unique) properties.…”
Section: Introductionmentioning
confidence: 99%
“…It means that, in addition to the reproducible preparation protocol, the characterization of prepared materials and the study of their macroscopic and microscopic properties and of their structure both on large and on the nanometer scales have to be performed in great detail. The differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), thermogravimetry analysis (TGA), and tensile characterization are the most important methods of material characterization that have been widely used for studying broad diversity of macroscopic functional properties in PUE systems.…”
Section: Introductionmentioning
confidence: 99%
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