“…11 CANs rely on dynamic covalent bonds that can break/reform and recombine either autonomously or with appropriate stimuli (esp. light 12,13 and heat 14−16 ), endowing polymers with unprecedented properties, such as self-healing, 14,17,18 recyclability, 19,20 weldability, 21 and reprocess-abIlity. 22−24 So far, many dynamic covalent bonds, such as Diels−Alder, 25,26 transesterification, 27,28 carbamate bonds, 29 thiol−ene click reactions, 30 disulfide bonds, 31−33 thiocarbamate bonds, 34−36 thiol−anhydride, 37 transimination, 38 boronic esters, 39,40 siloxane exchange, 41 and hindered urea bonds, 42 have been applied to design the thermosetting polymers with various types of CANs.…”