The enhancement of electromagnetic wave absorption at high-temperature as well as oxidation is cutting-edge issue in current electromagnetic functional materials due to the strong demand of stealth aircrafts or aero-engines working in harsh environments. In this contribution, the excellent electromagnetic wave absorption at 1158 K (885 C) with a minimum reflection coefficient (RC min ) of À12.62 dB and a wide effective absorption bandwidth (RC min < -10 dB) of 3.2 GHz was achieved on iron-containing siliconboron carbonitride (SiBCN) monolithic ceramics by using polymer-derived ceramics (PDC) route, setting a new record for EM wave absorption materials at high-temperature. In addition, these materials exhibited desirable mechanical properties and excellent hightemperature resistance until 1400 C in argon atmosphere and 885 C in air atmosphere, respectively. This ingenious strategy is generally benefiting the promotion of EM wave absorption materials with great potential in antenna housings, radomes, areo-engines, and stealth aircrafts in harsh environments.With rapid development of electronic equipments in wireless communication, medical and aerospace fields, electromagnetic (EM) wave transparency, absorption, and shielding are important issues. [1][2][3][4] EM wave absorbing materials are mainly deployed in high-power electronic instruments, satellite communication, radar, stealth ships, and aircrafts, which can eliminate adverse EM waves by converting into thermal energy. However, the stealth aircrafts or aero-engines are working in harsh environments such as high temperature and oxidation, the enhancement of electromagnetic wave absorption and stealth performance at high temperature more than 600 C (873 K) is cutting-edge issue in current electromagnetic functional materials.In this field, metamaterials, ferrites, carbon family materials (carbon black, carbon fibers (CFs), carbon nanotubes (CNTs), graphite flakes, graphene foams, or graphenes), metal-carbon nano-hybrids (Fe 3 O 4 /CNTs/CFs, Fe 3 O 4 /graphene capsules, Co-carbon nanotubes-graphene, Co-Carbon metal-organic framework), core/shell hierarchical nanostructures and dielectronic ceramics, 2D transition metal carbides (MXenes) show favorable EM absorbing performance in ambient environment. [5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] However, at high temperature more than 873 K (600 C), most of ferrites are limited by low Curie temperature (T c ), for example, 360-440 C for Ba 3 Me 2-Fe 24 O 41 (Me ¼ Co, Cu, Ni) and 570 C for Ni-Zn ferrites. [5] Above T c , the ferrite will be converted to paramagnetic and lose EM wave absorption functionality. For metamaterials, MXenes, and carbon family materials, they always suffer from the thermolysis and oxidation at high temperature more than 600 C (873 K).With resistance to both high temperature and oxidation, silicon carbide (SiC) or silicon nitride (Si 3 N 4 )-based ceramics are important dielectronic type EM wave absorbing materials in harsh environments. The SiC-based materials, including SiC ...