Ni(II) O,O-Alylene dithiophosphates and their adducts with nitrogen bases

Bhasin, C. P.; Srivastava, G.; Mehrotra, R. C.

doi:10.1016/s0020-1693(00)82590-6

Cited by 31 publications

(7 citation statements)

References 6 publications

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“…[Pb(L [2,3,9,10,13,14,20,21][4,8,15,19]tetraaza [1,11,12,22] tetra thiacyclodiicosane [5,7,16,18] tetraone}. L 2 = Macrocyclic ligand derived from bis-(2aminophenyl) disulphide and succinic acid (n=2), 24-membered ring; {Tetrabenzo [2,3,10,11,14,15,22,23][4,9,16,21]tet raaza [1,12,13,24]tetrathiacyclotetraicosane [5,7,1 7,20]tetraone}.…”

Section: Synthesis Of Precursormentioning

confidence: 99%

“…L 2 = Macrocyclic ligand derived from bis-(2aminophenyl) disulphide and succinic acid (n=2), 24-membered ring; {Tetrabenzo [2,3,10,11,14,15,22,23][4,9,16,21]tet raaza [1,12,13,24]tetrathiacyclotetraicosane [5,7,1 7,20]tetraone}. L 3 =Macrocyclic ligand derived from bis-(2aminophenyl) disulphide and glutaric acid (n=3), 26-membered ring; {Tetrabenzo [2,3,11,12,15,16,24,25][4,10,17,23]te traaza [1,13,14,26]tetrathiacyclohexaicosane [5,9,18,22]tetraone}.…”

Section: Synthesis Of Precursormentioning

confidence: 99%

“…{Tetrabenzo [2,3,12,13,16,17,26,27][4,11,18,25]te traaza [1,14,15,28]tetrathiacyclooctaicosane [5,10,19,24]…”

Section: Synthesis Of Precursormentioning

confidence: 99%

“…In spite of vast innovation in macrocyclic chemistry and tremendous interest in mixed ligand complexes, no mixed ligand macrocyclic complex was reported till our publications. Alkylene dithiophosphate has been the area of our thrust since last 3 decades [5][6][7][8][9][10][11][12][13][14]. Considering the importance of mixed ligand macrocyclic complexes, we reported synthesis, characterization, antimicrobial of Cr(III), Mn(II), Fe(III), Co(III), Ni(II), Cu(II), Cd(II), Sn(II) and Pb(II) with dialkylene and alkylene dithiophosphate having N 2 S 2 potential donors in 14 to 20 membered rings [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32].…”

Section: Introductionmentioning

confidence: 99%

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Synthesis, Characterization and Biological Screening of Alkylene Dithiophosphate Derivatives of Macrocyclic Complexes of Pb (II)

Prajapati¹,

Pathan

Bhasin

2021

JPRI

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Alkylenedithiophosphate derivatives of macrocyclic complexes of Pb (II), having N4S4 potential donors, of the general formula, [Pb(L){S2P(OR)2}2] where L=macrocyclic ligands L1, L2, L3, L4 and L5; R= C2H5-, C3H7n or C3H7i have been synthesized from the reaction of [Pb(L)X2(where X= Clˉ, NO3ˉ or CH3COOˉ) with sodium Alkylenedithiophosphate in 1:2 molar ratios in THF. These complexes have been characterized by elemental analysis, molar conductance, molecular weight determinations, IR, 1H, 13C NMR. Macrocyclic Complexes of Pb (II) derivatives have been studied by screening them Aspergillus flavus, Fusarium oxysporum, Alternaria alternata and bacteria like Salmonella typhi and Bacillus subtili. Alkylenedithiophosphate derivatives were found to be more fungitoxic and antibacterial than their corresponding macrocyclic complexes.

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Section: Synthesis Of Precursormentioning

confidence: 99%

Section: Synthesis Of Precursormentioning

confidence: 99%

“…{Tetrabenzo [2,3,12,13,16,17,26,27][4,11,18,25]te traaza [1,14,15,28]tetrathiacyclooctaicosane [5,10,19,24]…”

Section: Synthesis Of Precursormentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Synthesis, Characterization and Biological Screening of Alkylene Dithiophosphate Derivatives of Macrocyclic Complexes of Pb (II)

Prajapati¹,

Pathan

Bhasin

2021

JPRI

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“…4 A large number of antimony compounds have also been tested as bactericides, 5 fungicides, 6 and antifertility agents. 7 Cyclic O,O -alkylenedithiophosphates of transition metals have been extensively studied, [8][9][10] and the studies have also been extended to the derivatives of nontransition metals, including organoantimony(III) moieties. [11][12][13][14][15][16][17] Metal derivatives of antimony(III) containing alkylenedithiophosphates also exhibit significant antimicrobial activities.…”

Section: Introductionmentioning

confidence: 99%

Mixed Chloro Bis[Alkylenedithiophosphato] Antimony(III) and Their Heterobinuclear Derivatives with Boron Tetraisopropoxide: Synthesis and Characterization

Agrawal

Sharma

Singh

et al. 2010

Phosphorus, Sulfur, and Silicon and the Related Elements

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Chloro bis(alkylenedithiophosphato)antimony(III) complexes of the type [OGOP(S)S] 2 SbCl(1-5) [where G = C(Me) 2 CH 2 CH(Me) {1} C(Me) 2 C(Me) 2 {2}, CH 2 C(Me) 2 CH 2 {3}, CH(Me) CH(Me) {4} and -CH(Me) CH 2 CH 2 {5}] have been synthesized by the reaction of SbCl 3 with sodium salts of alkylenedithiophosphoric acids in a 1:2 molar ratio in refluxing benzene. Reactions of chloro bis(alkylenedithiophosphato) antimony(III) compounds, [OGOP(S)S] 2 SbCl with sodium tetraisopropoxoborate, NaB(OPr i ) 4 , in a 1:1 molar ratio in refluxing benzene yielded some new heterobinuclear derivatives of antimony(III) and boron(III) of the type[OGOP(S)S] 2 Sb(µ OPr i ) 2 B(OPr i ) 2 . These newly synthesized complexes have been characterized by elemental analysis and molecular weight measurement, and their plausible structures have been proposed on the basis of IR, NMR ( 1 H, 13 C, 31 P, 11 B), and FAB-mass spectral studies. On the basis of the spectroscopic evidence, a pseudo octahedral geometry around antimony and tetrahedral geometry around boron atom has been proposed. Cyclic O,O -alkylenedithiophosphate ligands and their corresponding chloro bis(alkylenedithiophosphato)antimony(III) compounds have been screened for microbial activities. These compounds showed significant antifungal activity against Fusarium and Trichoderma and antibacterial activity against E. Coli and Pseudomonas.

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ChemInform Abstract: NICKEL(II) O,O‐ALKYLENE DITHIOPHOSPHATES AND THEIR ADDUCTS WITH NITROGEN BASES

Bhasin¹,

Srivastava²,

Mehrotra³

1983

Chemischer Informationsdienst

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Ni(II) O,O-Alylene dithiophosphates and their adducts with nitrogen bases

Cited by 31 publications

References 6 publications

Synthesis, Characterization and Biological Screening of Alkylene Dithiophosphate Derivatives of Macrocyclic Complexes of Pb (II)

Synthesis, Characterization and Biological Screening of Alkylene Dithiophosphate Derivatives of Macrocyclic Complexes of Pb (II)

Mixed Chloro Bis[Alkylenedithiophosphato] Antimony(III) and Their Heterobinuclear Derivatives with Boron Tetraisopropoxide: Synthesis and Characterization

ChemInform Abstract: NICKEL(II) O,O‐ALKYLENE DITHIOPHOSPHATES AND THEIR ADDUCTS WITH NITROGEN BASES

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