1971
DOI: 10.1021/es60052a002
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Nitric acid and the nitrogen balance of irradiated hydrocarbons in the presence of oxides of nitrogen

Abstract: This restricts the sample size, resulting in a lowered effective sensitivity. An alternate technique could be the use of glacial HOAc as the extraction solvent. If the material were dissolved directly into the acid, the reagent concentration could be adjusted accordingly, and considerable sensitivity could be gained. Because the Br determination can be accomplished in the presence of large excesses of C1, this method, coupled with a C1 analysis technique, can be used for measuring Cl/Br ratios. Acknowledgment … Show more

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Cited by 22 publications
(15 citation statements)
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“…oxidised disappeared from the gas phase under conditions where HNO, vapour, if formed, would have remained in the gas phase. Similar observations have been made by (Gay & Bufalini, 1971). When the reaction was carried out in the presence of an artificial aerosol (ammonium sulphate or ferric oxide), nitrate was collected on the aerosol particles.…”
Section: Conversion Of Gaseous Sulphur Dioxide and Nitrogen Dioxide 237supporting
confidence: 90%
“…oxidised disappeared from the gas phase under conditions where HNO, vapour, if formed, would have remained in the gas phase. Similar observations have been made by (Gay & Bufalini, 1971). When the reaction was carried out in the presence of an artificial aerosol (ammonium sulphate or ferric oxide), nitrate was collected on the aerosol particles.…”
Section: Conversion Of Gaseous Sulphur Dioxide and Nitrogen Dioxide 237supporting
confidence: 90%
“…Similar observations have been made by (Gay & Bufalini, 1971). When the reaction was carried out in the presence of an artificial aerosol (ammonium sulphate or ferric oxide), nitrate was collected on the aerosol particles.…”
Section: Conversion Of Gaseous Sulphur Dioxide and Nitrogen Dioxide 237supporting
confidence: 90%
“…The inhibitive effect of hc was shown more clearly at the higher hc levels (Figure 5) and pre- Nitrogen dioxide accounted for less than one half of the NO,, present in the initial chamber charge. Of the nitrogen compounds known to form in such reaction systems (namely, peroxyacyl, alkyl, and inorganic nitrates), only pan, ppn, and inorganic nitrates were expected to affect nitrogen balance significantly (Altshuller et al, 1970;Gay and Bufalini, 1969).…”
Section: Resultsmentioning
confidence: 99%