Nitrosoderivate der Phenarsazin‐Reihe. Einwirkung von Nitrosylchlorid auf Derivate des dreiwertigen Arsens

Rasuwajew, G.; Godina, D. A.

doi:10.1002/cber.19320650433

Cited by 3 publications

(2 citation statements)

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“…In the case of N-nitrosodiphenylamine, no hydrochloride can be isolated, even at 0°C., the reaction proceeding directly to diphenylamine and nitrosyl chloride. Nitrosyl chloride has been formed from hydrogen chloride and other nitrosoamines (211,400).…”

Section: Inorganic Nitritesmentioning

confidence: 99%

“…Nitrosyl chloride reacts with zinc ethyl to form a metallic derivative readily converted to the A-dialkylhydroxylamine (75). Nitrosyl chloride reacts with trivalent arsenic compounds such as 10-methyl-5,10-dihydrophenarsazine, triphenylarsine, and diphenylchloroarsine in organic media to form 10-methyl-10-chloro-10-hydroxy-5, 10-dihydrophenarsazine, triphenylchlorohydroxyarsine, and tetraphenyltetrachloroarsine oxide, respectively (400). Diphenylmercury reacts with nitrosyl chloride, as the SnCLi-2NOCl complex, to form nitrosobenzene (22).…”

Section: Hydroxylamine Derivativesmentioning

confidence: 99%

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Nitrosyl Chloride.

Beckham¹,

Fessler²,

Kise³

1951

Chem. Rev.

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Section: Inorganic Nitritesmentioning

confidence: 99%

Section: Hydroxylamine Derivativesmentioning

confidence: 99%

Nitrosyl Chloride.

Beckham¹,

Fessler²,

Kise³

1951

Chem. Rev.

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Über antimonorganische Verbindungen

Kolditz¹,

Gitter²,

Rösel³

1962

Zeitschrift anorg allge chemie

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ring of 1 (mean values 207.3(7) and 192.5(7) pm), which, however, can only be referred to for comparison with care because of the different orientation (apical and equatorial in 1, apical in 3a). The formation of unsymmetrical Sb-0 -S b bridges in 3a can be attributed to the positive partial charge of the outer antimony atoms. This elicits a stronger interaction between metal atom and the lone pair of the bridge oxygen atom and a strengthening of the p-0-Sb bond.Experimental 3: A subpension of 1 (1.107 g, 1.5 mmol) 12, 41 and 2a (0.496 g, 2 mmol) or 2b (0.586 g. 2 mmol) in acetone (15 mL) was prepared at room temperature. After a short time a clear yellow solution formed, which, after addition of 10 m L of 2.2-dimethoxypropane. was stirred overnight and finally evaporated down under vacuum to about 10 mL. The precipitated microcrystalline, y e l l o~ powder was filtered off and washed with a small amount of ether. M p.: 3a 204-206°C (decomp.): 3b 202-206°C (decomp.): yield 3a 30%; 3b 3 Z"' 0.

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Optically Active Amines. 40.¹ Application of the Benzene Sector Rule to the Circular Dichroism of Chiral Benzylcarbinamines and Benzylcarbinols

Smith

Neergaard

1996

J. Am. Chem. Soc.

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The sign of the 1 L b Cotton effects (CEs) from about 240 to 270 nm in the circular dichroism (CD) of enantiomers of chiral benzylcarbinamines and benzylcarbinols is correlated with their absolute configurations using the benzene sector rule and a consideration of the equilibrium between their two conformers of lowest energy and of oppositely signed rotatory powers. For chiral benzylalkylcarbinamines, carbinamine salts, and carbinols, which show a single sign for their 1 L b CEs, a shift in the conformational equilibrium can explain a sign reversal of the CEs with a change in solvent, (R)-2-amino-1-phenylpropane showing negative 1 L b CEs in methanol but positive ones in cyclohexane. L-Phenylalanine in water shows positive 1 L b CEs, but in methanol it shows both negative and positive CD maxima. In methanol, the two longest wavelength maxima comprise a double CE associated with the band origin absorption maximum at 267 nm, the conformational equilibrium shifted from the positive conformer of L-phenylalanine to its negative one and the greater amount of the latter is now detected at slightly longer wavelength in the CD spectrum.

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Nitrosoderivate der Phenarsazin‐Reihe. Einwirkung von Nitrosylchlorid auf Derivate des dreiwertigen Arsens

Cited by 3 publications

References 4 publications

Nitrosyl Chloride.

Nitrosyl Chloride.

Über antimonorganische Verbindungen

Optically Active Amines. 40.¹ Application of the Benzene Sector Rule to the Circular Dichroism of Chiral Benzylcarbinamines and Benzylcarbinols

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Nitrosoderivate der Phenarsazin‐Reihe. Einwirkung von Nitrosylchlorid auf Derivate des dreiwertigen Arsens

Cited by 3 publications

References 4 publications

Nitrosyl Chloride.

Nitrosyl Chloride.

Über antimonorganische Verbindungen

Optically Active Amines. 40.1 Application of the Benzene Sector Rule to the Circular Dichroism of Chiral Benzylcarbinamines and Benzylcarbinols

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Optically Active Amines. 40.¹ Application of the Benzene Sector Rule to the Circular Dichroism of Chiral Benzylcarbinamines and Benzylcarbinols