This chapter shines a light on the critical role of women's governance during COVID-19, the Complex nexus of psychology, society, and Governance. The COVID-19 pandemic has dramatically transformed the educational landscape worldwide, Presenting unprecedented challenges and pressure. This pandemic is, no doubt, a threat to humanity (Poon & Peiris, 2020). Female leaders in education sectors across various countries have been instrumental in shaping responses to the pandemic, often demonstrating a unique blend of empathy, resilience, and strategic foresight. This chapter delves into the complex nexus of psychology society and governance, exploring how women's governance has influenced the educational sectors during COVID-19, the societal perceptions and pressures faced by these leaders, and the psychological ramifications of their roles. The COVID-19 pandemic also brought unprecedented challenges to educational systems worldwide, exposing and exacerbating existing inequalities.