Non-isothermal crystallization of biopolyesters of poly(butylene succinate) formed via in-situ polymerization in presence of poly(vinyl butyral)

Sun, Huan; Luo, Yi; Yang, Biao; Zhang, Huijuan; Huang, Jingsong

doi:10.1016/j.polymer.2018.08.035

Cited by 3 publications

(8 citation statements)

References 79 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Adding PVB greatly reduced spherulitic sizes and increased the peak temperature of crystallization [111]. An optimal content was observed for a minimal size of spherulites, and the PVB with a low molecular weight led to a smaller spherulitic size than its counterpart of a high molecular weight did [111]. A molecular model was proposed to explain accelerated nucleation and spherical growth from PVB's structural perspective.…”

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

“…Sun et al [111] investigated non-isothermal crystallization of biopolyesters of PBS formed via in situ polymerization in the presence of poly(vinyl butyral) (PVB). The effects of the PVB content and molecular weights on non-isothermal crystallization and mechanical properties were examined in detail [111]. Adding PVB greatly reduced spherulitic sizes and increased the peak temperature of crystallization [111].…”

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

“…The effects of the PVB content and molecular weights on non-isothermal crystallization and mechanical properties were examined in detail [111]. Adding PVB greatly reduced spherulitic sizes and increased the peak temperature of crystallization [111]. An optimal content was observed for a minimal size of spherulites, and the PVB with a low molecular weight led to a smaller spherulitic size than its counterpart of a high molecular weight did [111].…”

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

“…A molecular model was proposed to explain accelerated nucleation and spherical growth from PVB's structural perspective. The nucleated PBS exhibited a considerable improvement in mechanical properties [111]. The design and synthesis of a new PBS ionomer containing a novel bisfunctional phosphinate monomer, potassium salt of 10H-phenoxaphosphine-2,8-dicarboxylic acid,10-hydroxy-,2,8-dihydroxyethyl ester,10--oxide (DHPPO-K) was studied by Xu et al [112].…”

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

See 3 more Smart Citations

Biodegradable polymers, current trends of research and their applications, a review

Čolnik

Knez-Hrnčič

Škerget

et al. 2020

CI&CEQ

View full text Add to dashboard Cite

Biodegradable polymers have been developed rapidly in the last years and are widely used today in the fields of pharmacy, clinical biomedicine, cosmetic, medical, packing industries, tissue engineering, agriculture and other areas. The interest in biodegradable polymers has been increasing, mainly due to rising oil prices, which is the basic feedstock of plastic derived from petroleum, and also due to the problem of the removal of waste plastics that accumulate in the environment. Biodegradable polymers have many advantages in contrast to synthetic polymers and can be decomposed in the environment to non-hazardous substances. Biodegradable polymers are classified into two classes based on their synthesis i.e., synthetic and natural polymers. They are derived either from petroleum resources or from biological resources. The following review presents an overview of the different biodegradable polymers and their properties, current scientific research, applications, global production of bioplastic and replacement of conventional plastic.

show abstract

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

Section: Poly(butylene Succinate) (Pbs)mentioning

confidence: 99%

See 2 more Smart Citations

Biodegradable polymers, current trends of research and their applications, a review

Čolnik

Knez-Hrnčič

Škerget

et al. 2020

CI&CEQ

View full text Add to dashboard Cite

show abstract

“…They found that the probability for two-dimensional crystal growth increases, especially at higher heating rates, and also that the substitution of zinc ions by europium ions in Zn 2 SiO 4 matrix can lead to some crystal defects. Sun et al applied poly(vinyl butyral) as a nucleating agent into the monomers prior to polymerization of poly(butylene succinate) for accelerating crystallization and enhancing mechanical properties [ 38 ]. The nucleated poly(butylene succinate) exhibited a considerable improvement in mechanical properties.…”

Section: Basic Researchmentioning

confidence: 99%

Application of Polymers as a Tool in Crystallization—A Review

et al. 2021

View full text Add to dashboard Cite

The application of polymers as a tool in the crystallization process is gaining more and more interest among the scientific community. According to Web of Science statistics the number of papers dealing with “Polymer induced crystallization” increased from 2 in 1990 to 436 in 2020, and for “Polymer controlled crystallization”—from 4 in 1990 to 344 in 2020. This is clear evidence that both topics are vivid, attractive and intensively investigated nowadays. Efficient control of crystallization and crystal properties still represents a bottleneck in the manufacturing of crystalline materials ranging from pigments, antiscalants, nanoporous materials and pharmaceuticals to semiconductor particles. However, a rapid development in precise and reliable measuring methods and techniques would enable one to better describe phenomena involved, to formulate theoretical models, and probably most importantly, to develop practical indications for how to appropriately lead many important processes in the industry. It is clearly visible at the first glance through a number of representative papers in the area, that many of them are preoccupied with the testing and production of pharmaceuticals, while the rest are addressed to new crystalline materials, renewable energy, water and wastewater technology and other branches of industry where the crystallization process takes place. In this work, authors gathered and briefly discuss over 100 papers, published in leading scientific periodicals, devoted to the influence of polymers on crystallizing solutions.

show abstract

Polybutylene succinate, a potential bio-degradable polymer: synthesis, copolymerization and bio-degradation

Savitha¹,

Paghadar

Kumar

et al. 2022

Polym. Chem.

View full text Add to dashboard Cite

show abstract

Non-isothermal crystallization of biopolyesters of poly(butylene succinate) formed via in-situ polymerization in presence of poly(vinyl butyral)

Cited by 3 publications

References 79 publications

Biodegradable polymers, current trends of research and their applications, a review

Biodegradable polymers, current trends of research and their applications, a review

Application of Polymers as a Tool in Crystallization—A Review

Polybutylene succinate, a potential bio-degradable polymer: synthesis, copolymerization and bio-degradation

Contact Info

Product

Resources

About