Magnetic, thermal, and electric properties of alloys of the systems FeNi, NiCr, FeNi‐Mn, and FeNi‐Cr are studied. Itis shown that in alloys of the systems FeNi and NiCr, spin glass does not appear. The form of phase diagrams of the quasi‐binary systems Mn20FexNi80 − xFe50Ni5o −xMnx, Fe65Ni35 −xCrx, and Cr10FexNi90 −x is determined. The diagrams are compared with the character of variation of susceptibility, heat capacity, and magnetoresistance at a concentration magnetic transition. The investigationof the behaviour of nonlinear susceptibility of FeNiCr(Mn) spin glasses in the vicinity of the ‘freezing’ point, Tf, provides evidence for the presence of a phase transition. The variation in the properties at the double temperature transition, paramagnetism‐ferromagnetism‐spin glass is considered.