In this paper, we investigate pulsed eddy current (PEC) testing based on a rectangular sensor for the purpose of defect shape mapping in electric vehicle lightweight alloy material. Different dimensional defects were machined on the 3003 aluminum alloy and detected using the A-scan technique and C-scan imaging in two scanning directions. The experiment results indicated that defect plane shape could be preliminarily obtained and length and width could be estimated based upon C-scan contour images. Consequently, the comparison of results between the two directions showed that the C-scan identification in the direction of magnetic flux was better than in the direction of the exciting current. Finally, subsurface defects and irregular defects were detected to verify the performance of shape mapping as a recommended approach. The conclusion drawn indicates that the proposed method, based on PEC rectangular sensors, is an effective approach in reconstructing a defect’s shape.