Abstract. Thermal stability of the enclosure structures is one of the most important objective in the building design. Thermal processes in the wall depend not only on the internal and external air temperature, but also on many other factors. Therefore, complexity of this process make heat conservation in the room to be an actual problem. This paper presents dependence between thermal stability of the enclosure structure and its design. It was shown that thermophysical characteristics of materials directly affect the thermal processes in the wall. For the research, three frequently used types of enclosure structure in Russia were taken. For each wall was found the average temperature and cooling time. As a result, it was found that the higher values of thermal conductivity, specific heat and material density are, the higher average temperature of the wall is.