Nouvelles familles de phases MIMII2Nb3O10 a feuillets “perovskites”

Ion-Exchange Reaction of n-Pentylamine-Intercalated Layered Perovskite with Alkali and Alkaline Earth Metal Ions in Aqueous Solution

“…The XRD patterns of KCa2Nb3O10 and HCa2Nb3O10 dried at 383 K were in good agreement with those reported in the literature [1][2][3]. Although the wet HCa2Nb3O10 contained 1.5 molecules of 1120, conversion to the anhydrate at 363 K was confirmed by the TG-DTA measurements.…”

Designed Reversible Alkylamine Intercalation–Deintercalation in the Layered Perovskite‐Type Oxide KCa2Nb3O10

“…[2,19,20] Interestingly, the coordinating geometry of the interlayer A atom is heavily size-dependent. While the large cations of Cs and Rb reside in a distorted cubic site, [20] the small Li ion prefers to fill the tetrahedral site between adjacent perovskite layers.…”

Photocatalytic Activities of Layered Niobate Perovskite (A'An^|^minus;1NbnO3n+1, A: Ca, La) with Substitution of Ti and W for Nb

“…Among the many explored photocatalysts, layered metal-oxides have shown much promise in exhibiting some of the highest photocatalytic rates and quantum efficiencies for the degradation of organics, including 20,21) . The Dion-Jacobson series of layered perovskites has one interlayer cation per formula unit 22,23) . Ruddlesden-Popper phases A ' 2 (A n-1 B n O 3n+1 ) have two interlayer cations per formula unit and possess twice the interlayer charge density of the Dion-Jacobson phases 24,25) .…”