2015
DOI: 10.1016/j.memsci.2015.07.056
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Novel concept of polymer electrolyte membranes for high-temperature fuel cells based on ETFE grafted with neutral acrylic monomers

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Cited by 19 publications
(6 citation statements)
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“…1), as the reactivity ratios for both monomers are close to unity in BuOH. The copolymerization of HEA and HEMA was found to follow a typical acrylate/methacrylate behaviour, 43 consistent with the idea that the H-bonding equally influenced the reactivity of both monomers. The postulated substitution and disruption mechanism is confirmed by the PLP-SEC experiments performed in DMF, also shown in Fig.…”
supporting
confidence: 85%
“…1), as the reactivity ratios for both monomers are close to unity in BuOH. The copolymerization of HEA and HEMA was found to follow a typical acrylate/methacrylate behaviour, 43 consistent with the idea that the H-bonding equally influenced the reactivity of both monomers. The postulated substitution and disruption mechanism is confirmed by the PLP-SEC experiments performed in DMF, also shown in Fig.…”
supporting
confidence: 85%
“…One example are strategies employing a commercial poly(ethylene-alt-tetrafluoroethylene) (ETFE) base material. Previously, we reported on high temperature polymer electrolyte membranes (HTPEM) based on induced graft copolymerization of (meth)acrylate monomers on ETFE backbone material after electron beam (EB) treatment and subsequent doping with phosphoric acid [31,32]. In contrast, generally PEMs with an operating temperature below 100 °C (low temperature polymer electrolyte membranes, LTPEM) contain sulfonic acid groups, which are nowadays most commonly used in fuel cell vehicles.…”
Section: Introductionmentioning
confidence: 99%
“…Several works is using fuel cell to storage energy and membranes with conducting polymers [9,10,11]. This field is very import to the future because limited fossil fuel supply [12][13][14][15][16][17].…”
Section: Introductionmentioning
confidence: 99%