Novel hybrid epoxy silicone materials as efficient anticorrosive coatings for mild steel

Abstract

Novel hybrid organic–inorganic coatings were successfully prepared, coated on mild steel, and subjected to different spectral, electrochemical and morphological characterizations.

Hybrid organosiloxane material/metal oxide composite as efficient anticorrosive coatings for mild steel in a saline medium

“…The preparation of the hybrid FT polymeric sol–gel materials was attained via the hydrolysis/polycondensation sol–gel reactions of the TEOS, DMMOMS, and APTMS silane precursors. Previously reported hybrid polymers made of one or two of these silane precursors were reported to have high desired crosslink density properties . The obtained hybrid polymer from the above precursors was allowed to react further with PDMS to induce more hydrophobic and scratch resistance characters in the final polymer.…”

“…Previously reported hybrid polymers made of one or two of these silane precursors were reported to have high desired crosslink density properties. 11,[17][18][19] The obtained hybrid polymer from the above precursors was allowed to react further with PDMS to induce more hydrophobic and scratch resistance characters in the final polymer. The post-modification of TEOS during the synthesis of the hybrid polymeric material with other silane precursors such as methyltrimethoxysilane, 3glycidoxypropyltrimethoxysilane, 3-Isocyanatopropyltriethoxysilane, and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane produced hybrid silica polymers either with low corrosion protection properties or phase instability.…”

“…These exciting materials have combined and preferred properties of organic polymers (e.g., flexibility, ductility, dielectric) and inorganic silica (e.g., high thermal stability, strength, hardness, UV–vis absorbance), with a very promising application as protective coatings for various metallic substrates . Hybrid organic‐inorganic silica materials are mainly produced through the hydrolysis and polycondensation reactions of organofunctional alkoxysilane precursors . The desired hydrophobic, mechanical, barrier and adhesion properties of a hybrid coating can be adjusted by controlling the chemistry of its organic and inorganic components…”

“…[7][8][9] Hybrid organic-inorganic silica materials are mainly produced through the hydrolysis and polycondensation reactions of organofunctional alkoxysilane precursors. 10,11 The desired hydrophobic, mechanical, barrier and adhesion properties of a hybrid coating can be adjusted by controlling the chemistry of its organic and inorganic components. 12 properties of the loaded polymer on mild steel substrate in the saline medium.…”

Effect of Graphene Oxide/ZSM-5 Hybrid on Corrosion Resistance of Waterborne Epoxy Coating

“…This behaviour was attributed to the crosslinking reaction between the filler and epoxy resin and to the polar force provided by the polar groups (hydroxyl) of the filler. This can be explained by the availability of more free GO-OH groups in this coating to bond to steel surface [32].…”