a b s t r a c tThe complete range of Ti 5 Si 3 eTi 5 Ge 3 solid solutions was synthesised from elemental mixtures of Ti, Si, and Ge under an inert atmosphere via mechanically induced self-sustaining reactions (MSR). The stoichiometry of Ti 5 Si 3Àx Ge x solid solutions was controlled by adjusting the Si/Ge ratio of the initial mixture. The chemical composition and lattice parameters of the materials confirmed that Ti 5 Si 3 eTi 5 Ge 3 solid solutions with good chemical homogeneity could be produced via MSR.