Nanocube has attracted interest regarding its synthesis by the wet chemical process. Recently, nanocube with perovskite structure such as barium titanate (BaTiO3) and strontium titanate (SrTiO3) has been studied. In this study, sodium niobate (NaNbO3) was prepared by the solvothermal method and its morphology was investigated. The synthesis was carried out using niobium oxide (Nb2O5) and sodium hydroxide (NaOH) as starting materials, also using ethanol as solvent. X-ray diffraction (XRD) confirmed the presence of perovskite NaNbO3 particles and indicated that the phase is orthorhombic NaNbO3. Scanning electron microscopy (SEM) observation revealed the form of NaNbO3 to be nanocube. Reaction times and concentrations of reaction solutions are important factors for synthesis of nanoparticles. The particle size increases with the reaction times, while the particle size decreases with the concentration of the reaction solutions. The smaller crystals were synthesized in a shorter reaction time at the higher concentration of the reaction solutions.