“…As the beginning of the 21st century, the rise of new energy, new engines, new marine industries, and other related industries makes thermal insulation materials a vital part in scientific and industrial processes. Among them, nano‐porous super thermal insulation material is one of important components, owing to its low bulk density, stable pore structure, and ultralow thermal conductivity, 1 which is widely used in aerospace crafts, 2 supercapacitor, 3 microsensors, and microsystems, 4 rendering it become one focal point of the current research.…”