1969
DOI: 10.1103/physrev.182.400
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Nuclear Spin Relaxation by Translational Diffusion in Liquid Ethane

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Cited by 175 publications
(60 citation statements)
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“…As recently demonstrated for simple (non-polymeric) liquids, the slow translational dynamics probed by the intermolecular relaxation dominates the 1 H relaxation dispersion at low frequencies [48][49][50][51][52], and this is also the case for polymers as discussed above. Applying eq.…”
Section: E D(tm)supporting
confidence: 61%
“…As recently demonstrated for simple (non-polymeric) liquids, the slow translational dynamics probed by the intermolecular relaxation dominates the 1 H relaxation dispersion at low frequencies [48][49][50][51][52], and this is also the case for polymers as discussed above. Applying eq.…”
Section: E D(tm)supporting
confidence: 61%
“…In this way, it was shown that intermolecular relaxation was normally the dominant relaxation mechanism in, for example, liquid ethane (Harmon and Muller, 1969) and solid benzene (Anderson, 1965). Further, a number of studies have shown the importance of translational motions in proton relaxation.…”
Section: Intermolecular Dipole-dipole Relaxationmentioning
confidence: 97%
“…Harmon and Muller (1969) have also considered the effect of a nonuniform spin density, but again the correction factor introduced is only a few percent.…”
Section: Intermolecular Dipole-dipole Relaxationmentioning
confidence: 98%
“…(40b) is the result of the averaging procedure performed using a model distribution function taken from Ref. [88], p, is the nwnber density of the probe particles (in neat liquids p,=nNAIVM, NA is the Avogadro nwnber and VM the molar volume, n=l for molecular liquids, n=a+m for the MaAm molten salt), and l;(lp8) is the length of the vectors defining the positions of i or p atoms with respect to the center of mass of the molecule studied or molecule B.…”
Section: Spectral Shifts Caused By Repulsion Forcesmentioning
confidence: 99%