The formation of hydrogen ͑H͒-related complexes and H effects on boron ͑B͒ and phosphorus ͑P͒ dopants was investigated in B-or P-doped silicon ͑Si͒ crystal treated with high concentration of H. The reactivation process of dopant carriers by annealing after hydrogenation was significantly different between the p-type and n-type specimens. The difference is likely to be attributable to the formation of H-related defects based on the stable sites of the H atoms, i.e., complicated H multiple trapping centers are formed by bond breaking due to H atoms in only p-type B-doped Si.