Abstract:The nonlinear partial differential equations which describe transient photoconductivity in insulators are solved numerically. Trapping and recombination are included which allows photoconduction to be studied in the presence of large space charge. Use of methods for ‘‘stiff’’ differential equations insures stable time dependent solutions even for problems which have widely different time constants. The program is applied to a thin film (1000 Å) of silicon dioxide to illustrate the salient features of the numer… Show more
“…Photovoltaic cells of a blend of poly(2-methoxy-5-(3¢,7¢-dimethyloctyloxy)-p-phenylene vinylene) (MDMO-PPV) and [6,6]-phenyl C 61 -butyric acid methyl ester (PCBM) have thereby proven their capacity for solar-cell applications, exhibiting power-conversion efficiencies of around 3 % at the global AM1.5 (air mass 1.5) spectrum. [1,2] In a donor/acceptor organic photovoltaic cell, light absorption results in the formation of excitons that dissociate at the heterojunction interface by an ultrafast electron transfer from the donor to the acceptor (sub-picosecond range).…”
“…Photovoltaic cells of a blend of poly(2-methoxy-5-(3¢,7¢-dimethyloctyloxy)-p-phenylene vinylene) (MDMO-PPV) and [6,6]-phenyl C 61 -butyric acid methyl ester (PCBM) have thereby proven their capacity for solar-cell applications, exhibiting power-conversion efficiencies of around 3 % at the global AM1.5 (air mass 1.5) spectrum. [1,2] In a donor/acceptor organic photovoltaic cell, light absorption results in the formation of excitons that dissociate at the heterojunction interface by an ultrafast electron transfer from the donor to the acceptor (sub-picosecond range).…”
“…Actually, this calculation reproduces the analytical result of Sokel and Hughes. 8,14 From the difference between the dashed and dashed-dotted line, it is evident that Langevin recombination is the dominant loss mechanism in the entire measured bias range.…”
The photocurrent in polymer/fullerene blends is characterized as a function of bias at temperatures ranging from 125to300K. Assuming a constant generation rate and bimolecular recombination, the results are numerically modeled within the drift-diffusion approximation. Bimolecular recombination is found to be a dominant factor in the field dependence of the photocurrent in the entire measured voltage range. Inclusion of field dependent geminate pair dissociation and recombination via the Onsager expressions gives a much stronger field dependence than experimentally observed. From the temperature dependence of the extracted mobilities, we can simultaneously estimate the broadening of the transporting highest occupied and lowest unoccupied molecular orbital levels.
“…This behavior is caused by the opposite effect of drift and diffusion of charge carriers. 11 At V oc drift and diffusion balance and the current is zero. At higher effective voltage V oc − V Ͼ 0.1 V the drift contribution is dominant and the photogenerated current tends to saturate.…”
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