In this paper, the airport pavement concrete has been taken as the main research object, three kinds of absorbing materials, namely silicon carbide (SiC), iron oxide (Fe3O4) and graphite, have been respectively mixed into the concrete, and an open microwave testing system has been established. Based on this system, the basic mechanical properties, microwave heating characteristics, microwave deicing effect and its influencing factors of modified concrete are systematically studied. In addition, a comparative analysis of the influence mechanism of different absorbing materials on the strength and absorbing performance of pavement concrete is carried out. The results showed that the addition of SiC, Fe3O4, and graphite could effectively enhance the microwave effect of pavement concrete, and the more the addition, the more obvious the improvement. Furthermore, under the same mixing amount, the degree of improvement of microwave deicing performance of each absorbing material from large to small is graphite, Fe3O4, SiC. However, the addition of graphite will form several weak links in concrete, thereby reducing its overall mechanical properties. SiC can slightly improve the mechanical properties of pavement concrete, but it has no significant effect on the microwave absorption properties. With the addition of Fe3O4, the strength of concrete changes little, and the effect of microwave absorbing heating and microwave deicing is remarkable. In general, the comprehensive performance of microwave deicing of Fe3O4 modified concrete is optimal. This study has high scientific and practical significance, and can be widely applied to deicing projects on airports and high-grade highways.