Adding an initiator is an effective method
of promoting hydrocarbon pyrolysis and improving the heat sink of
fuels. Nitropropane was proposed as an initiator with good performance,
owing to its lower reaction activation energy for C–N bond
cleavage. To study the effects of this initiator on hydrocarbon pyrolysis,
a miniature tube reactor that can simulate a real heating procedure
in an aeroengine was used to investigate the n-decane
pyrolysis with and without nitropropane under experimental supercritical
conditions. The results demonstrate that the nitropropane initiator
promotes the pyrolysis of fuel as it flows through a tube with a large
length–diameter ratio within a certain temperature range. The
initial decomposition temperature of n-decane is
reduced by approximately 100 K, and the increase in the conversion
leads to a higher heat sink for n-decane, which can
result in decreases in the fuel and reactor temperatures under the
same heating condition and within the effective temperature range.
A stronger promoting effect can be achieved by increasing the concentration
of the nitropropane initiator. The variation laws for the n-decane pyrolysis reaction rate along the flow reactor
are changed by the initiator, the presence of nitropropane greatly
accelerates the pyrolysis reaction of fuel at a lower temperature,
and the opposite tendency appears as the fuel temperature increases,
which is caused by the consumption of the initiator. In addition,
the selectivity of methane, propane, and alkenes, especially ethylene,
increases because of the propyl radical generated by the C–N
dissociation of nitropropane before the initiator is consumed.