CO2 injection has been used to improve oil
recovery for the last 4 decades. In recent years, CO2 injection
has become more attractive because of the dual effect: injection in
the subsurface (1) allows for reduction of the CO2 concentration
in the atmosphere to reduce global warming and (2) improves the oil
recovery. One of the screening criteria for CO2 injection
as an enhanced oil recovery method is based on the measurement of
CO2 minimum miscibility pressure (MMP) in a slim tube.
The slim tube data are used for the purpose of field evaluation and
for the tuning of the equations of state. The slim tube represents
one-dimensional (1D) horizontal flow. When CO2 dissolves
in the oil, the density may increase. The effect of the density increase
in high-permeability reservoirs when CO2 is injected from
the top has not been modeled in the past. The increase in density
changes the flow path from 1D to two-dimensional (2D) and three-dimensional
(3D) (downward flow). As a result of this density effect, the compositional
path in a reservoir can be radically different from the flow path
in a slim tube. In this work, we study the density effect from CO2 dissolution in modeling of CO2 injection. We account
for the increase in oil density with CO2 dissolution using
the Peng–Robinson equation of state. The viscosity is modeled
based on the Pedersen–Fredenslund viscosity correlation. We
perform compositional simulation of CO2 injection in a
2D vertical cross-section with the density effect. Our results show
that the density increase from CO2 dissolution may have
a drastic effect on the CO2 flow path and recovery performance.
One conclusion from this work is that there is a need to have accurate
density data for CO2/oil mixtures at different CO2 concentrations to model properly CO2 injection studies.
Our main conclusion is that the downward flow of the CO2 and oil mixture may not be gravity-stable, despite the widespread
assumption in the literature.