Numerical Simulation of Methane and Propane Reforming Over a Porous Rh/Al2O3 Catalyst in Stagnation-Flows: Impact of Internal and External Mass Transfer Limitations on Species Profiles

Abstract

Hydrogen production by catalytic partial oxidation and steam reforming of methane and propane towards synthesis gas are numerically investigated in stagnation-flow over a disc coated with a porous Rh/Al2O3 layer. A one-dimensional flow field is coupled with three models for internal diffusion and with a 62-step surface reaction mechanism. Numerical simulations are conducted with the recently developed computer code DETCHEMSTAG. Dusty-Gas model, a reaction-diffusion model and a simple effectiveness factor model, are alternatively used in simulations to study the internal mass transfer inside the 100 µm thick washcoat layer. Numerically predicted species profiles in the external boundary layer agree well with the recently published experimental data. All three models for internal diffusion exhibit strong species concentration gradients in the catalyst layer. In partial oxidation conditions, a thin total oxidation zone occurs close to the gas-washcoat interface, followed by a zone of steam and dry reforming of methane. Increasing the reactor pressure and decreasing the inlet flow velocity increases/decreases the external/internal mass transfer limitations. The comparison of reaction-diffusion and Dusty-Gas model results reveal the insignificance of convective flow on species transport inside the washcoat. Simulations, which additionally solve a heat transport equation, do not show any temperature gradients inside the washcoat.

Recent Developments in Rh Heterogeneous Catalysts

“…Furthermore, it was demonstrated in two reviews that different oxide supports changed not only the conversion, but the selectivity and the mechanism of CO 2 hydrogenation and the dry reforming of methane when Rh-based catalysts were used [21,22]. The numerical simulation of methane and other reforming alkanes was carried out over the Rh/Al 2 O 3 catalyst in stagnation flows, emphasizing the importance of the impact of internal and external mass transfer [23]. The study of catalytic reactions of hydrogenation, including hydrodeoxygenation, was extended to several aromatics in the gas phase [24] and in liquid medium on Rh-based catalysts [25].…”