Double-diffusive convection is a form of fluid flow that occurs when two processes of molecular diffusion are active in a fluid at the same time, causing instabilities and also complicated behaviour. One chemical or biological species concentration can cause a flux of another species, either linearly or nonlinearly, a phenomenon known as cross-diffusion. The cross-diffusion effects on double-diffusive MHD fluid flow through the Hermite wavelet method is examined. The governing coupled partial differential equations of the problem under consideration are transformed to highly nonlinear ordinary differential equations over a finite domain with the help of similarity transformations. The results are obtained for the skin friction coefficient, as well as the velocity, temperature and the concentration profiles for some values of the governing parameters, namely, the cross diffusion terms, Hartmann number, thermophoresis parameter, squeeze number, Prandtl number and suction/injection parameter. The obtained results are validated against previously published results for special case of the problems.